Synthesis, crystal structure and magnetic property of the polymeric ribbon: [Co(ip)(phen)]n

You Fu Zhou; Qian Shi; Da Qiang Yuan; Yan Qing Xu; Mao Chun Hong

Synthesis, crystal structure and magnetic property of the polymeric ribbon: [Co(ip)(phen)]_n

You Fu Zhou^*
, Qian Shi
, Da Qiang Yuan
, Yan Qing Xu
, Mao Chun Hong

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

A metal-organic coordination polymer [Co(ip)(phen)]_n·(ip = isophthalate, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and characterized. Compound 1 crystallizes in P2/c space group with a = 8.37(2), b = 10.41(1), c = 18.36(3) Å, β = 100.41(7)°, C ₂₀H₁₂CoN₂O₄, M_r = 403.25, V = 1573(4) Å³, Z = 4 and D_c = 1.703 g/cm ³. Two Co(II) ions are bridged by μ-carboxylate to form a dinuclear unit, which is extended by ip ligands resulting in a ribbon-like chain. Pairs of phen ligands attach to the dinuclear units on both sides of the chain alternately. Magnetic study reveals that the interaction between the carboxylate-bridged Co(II) ions in 1 is weakly antiferromagnetic.

源语言	英语
页（从-至）	503-508
页数	6
期刊	Jiegou Huaxue
卷	24
期	5
出版状态	已出版 - 2005
已对外发布	是

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@article{97f2ac3c082343fbaf6fd63c87f25f21,

title = "Synthesis, crystal structure and magnetic property of the polymeric ribbon: [Co(ip)(phen)]n",

abstract = "A metal-organic coordination polymer [Co(ip)(phen)]n·(ip = isophthalate, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and characterized. Compound 1 crystallizes in P2/c space group with a = 8.37(2), b = 10.41(1), c = 18.36(3) {\AA}, β = 100.41(7)°, C 20H12CoN2O4, Mr = 403.25, V = 1573(4) {\AA}3, Z = 4 and Dc = 1.703 g/cm 3. Two Co(II) ions are bridged by μ-carboxylate to form a dinuclear unit, which is extended by ip ligands resulting in a ribbon-like chain. Pairs of phen ligands attach to the dinuclear units on both sides of the chain alternately. Magnetic study reveals that the interaction between the carboxylate-bridged Co(II) ions in 1 is weakly antiferromagnetic.",

keywords = "1,10-phenanthroline, Cobalt, Crystal structure, Isophthalate, Magnetism",

author = "Zhou, \{You Fu\} and Qian Shi and Yuan, \{Da Qiang\} and Xu, \{Yan Qing\} and Hong, \{Mao Chun\}",

year = "2005",

language = "English",

volume = "24",

pages = "503--508",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "5",

}

TY - JOUR

T1 - Synthesis, crystal structure and magnetic property of the polymeric ribbon

T2 - [Co(ip)(phen)]n

AU - Zhou, You Fu

AU - Shi, Qian

AU - Yuan, Da Qiang

AU - Xu, Yan Qing

AU - Hong, Mao Chun

PY - 2005

Y1 - 2005

N2 - A metal-organic coordination polymer [Co(ip)(phen)]n·(ip = isophthalate, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and characterized. Compound 1 crystallizes in P2/c space group with a = 8.37(2), b = 10.41(1), c = 18.36(3) Å, β = 100.41(7)°, C 20H12CoN2O4, Mr = 403.25, V = 1573(4) Å3, Z = 4 and Dc = 1.703 g/cm 3. Two Co(II) ions are bridged by μ-carboxylate to form a dinuclear unit, which is extended by ip ligands resulting in a ribbon-like chain. Pairs of phen ligands attach to the dinuclear units on both sides of the chain alternately. Magnetic study reveals that the interaction between the carboxylate-bridged Co(II) ions in 1 is weakly antiferromagnetic.

AB - A metal-organic coordination polymer [Co(ip)(phen)]n·(ip = isophthalate, phen = 1,10-phenanthroline) 1 has been hydrothermally synthesized and characterized. Compound 1 crystallizes in P2/c space group with a = 8.37(2), b = 10.41(1), c = 18.36(3) Å, β = 100.41(7)°, C 20H12CoN2O4, Mr = 403.25, V = 1573(4) Å3, Z = 4 and Dc = 1.703 g/cm 3. Two Co(II) ions are bridged by μ-carboxylate to form a dinuclear unit, which is extended by ip ligands resulting in a ribbon-like chain. Pairs of phen ligands attach to the dinuclear units on both sides of the chain alternately. Magnetic study reveals that the interaction between the carboxylate-bridged Co(II) ions in 1 is weakly antiferromagnetic.

KW - 1,10-phenanthroline

KW - Cobalt

KW - Crystal structure

KW - Isophthalate

KW - Magnetism

UR - https://www.scopus.com/pages/publications/20044378542

M3 - Article

AN - SCOPUS:20044378542

SN - 0254-5861

VL - 24

SP - 503

EP - 508

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 5

ER -

Synthesis, crystal structure and magnetic property of the polymeric ribbon: [Co(ip)(phen)]n

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Synthesis, crystal structure and magnetic property of the polymeric ribbon: [Co(ip)(phen)]_n