Synthesis and structure of [NH4]4H[PMo8VIV4V V2O42] · 24H2O

Yan Xu; Ji Qing Xu; Guo Yu Yang; Tei Gang Wang; Yan Xing; Yong Hua Ling; Heng Qing Jia

doi:10.1016/S0277-5387(98)00050-3

Synthesis and structure of [NH₄]₄H[PMo₈V^IV₄V ^V₂O₄₂] · 24H₂O

Yan Xu
, Ji Qing Xu^*
, Guo Yu Yang
, Tei Gang Wang
, Yan Xing
, Yong Hua Ling
, Heng Qing Jia

^*此作品的通讯作者

Jilin University
CAS - Changchun Institute of Applied Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

40 引用（Scopus）

摘要

[NH₄]₄H[PMo₈V^IV ₄V^V₂O₄₂] · 24H₂O has been hydrothermally synthesized from ammonium vanadate and sodium molybdate in aqueous solution by adding phosphorous acid, and its structure determined by single crystal X-ray analysis. The heteropoly molybdovanadophosphate anion is a bicapped 'pseudo-Keggin' polyanion, two vanadium atoms are distributed at two 'capping' metal atom positions and other four vanadium atoms randomly distributed at eight metal atom positions.

源语言	英语
页（从-至）	2441-2445
页数	5
期刊	Polyhedron
卷	17
期	15
DOI	https://doi.org/10.1016/S0277-5387(98)00050-3
出版状态	已出版 - 15 7月 1998
已对外发布	是

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@article{286acfe433da4283bdf1d96d69961bad,

title = "Synthesis and structure of [NH4]4H[PMo8VIV4V V2O42] · 24H2O",

abstract = "[NH4]4H[PMo8VIV 4VV2O42] · 24H2O has been hydrothermally synthesized from ammonium vanadate and sodium molybdate in aqueous solution by adding phosphorous acid, and its structure determined by single crystal X-ray analysis. The heteropoly molybdovanadophosphate anion is a bicapped 'pseudo-Keggin' polyanion, two vanadium atoms are distributed at two 'capping' metal atom positions and other four vanadium atoms randomly distributed at eight metal atom positions.",

keywords = "Bicapped 'pseudo-Keggin', Crystal structure, Hydrothermal synthesis, Molybdovanadophosphate",

author = "Yan Xu and Xu, \{Ji Qing\} and Yang, \{Guo Yu\} and Wang, \{Tei Gang\} and Yan Xing and Ling, \{Yong Hua\} and Jia, \{Heng Qing\}",

year = "1998",

month = jul,

day = "15",

doi = "10.1016/S0277-5387(98)00050-3",

language = "English",

volume = "17",

pages = "2441--2445",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "15",

}

TY - JOUR

T1 - Synthesis and structure of [NH4]4H[PMo8VIV4V V2O42] · 24H2O

AU - Xu, Yan

AU - Xu, Ji Qing

AU - Yang, Guo Yu

AU - Wang, Tei Gang

AU - Xing, Yan

AU - Ling, Yong Hua

AU - Jia, Heng Qing

PY - 1998/7/15

Y1 - 1998/7/15

N2 - [NH4]4H[PMo8VIV 4VV2O42] · 24H2O has been hydrothermally synthesized from ammonium vanadate and sodium molybdate in aqueous solution by adding phosphorous acid, and its structure determined by single crystal X-ray analysis. The heteropoly molybdovanadophosphate anion is a bicapped 'pseudo-Keggin' polyanion, two vanadium atoms are distributed at two 'capping' metal atom positions and other four vanadium atoms randomly distributed at eight metal atom positions.

AB - [NH4]4H[PMo8VIV 4VV2O42] · 24H2O has been hydrothermally synthesized from ammonium vanadate and sodium molybdate in aqueous solution by adding phosphorous acid, and its structure determined by single crystal X-ray analysis. The heteropoly molybdovanadophosphate anion is a bicapped 'pseudo-Keggin' polyanion, two vanadium atoms are distributed at two 'capping' metal atom positions and other four vanadium atoms randomly distributed at eight metal atom positions.

KW - Bicapped 'pseudo-Keggin'

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Molybdovanadophosphate

UR - https://www.scopus.com/pages/publications/0000625196

U2 - 10.1016/S0277-5387(98)00050-3

DO - 10.1016/S0277-5387(98)00050-3

M3 - Article

AN - SCOPUS:0000625196

SN - 0277-5387

VL - 17

SP - 2441

EP - 2445

JO - Polyhedron

JF - Polyhedron

IS - 15

ER -

Synthesis and structure of [NH4]4H[PMo8VIV4V V2O42] · 24H2O

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Synthesis and structure of [NH₄]₄H[PMo₈V^IV₄V ^V₂O₄₂] · 24H₂O