TY - JOUR
T1 - Synthesis and structure of Ag3PSe4
AU - Ma, Hong Wei
AU - Guo, Guo Cong
AU - Chen, Wen Tong
AU - Deng, Lei
AU - Zhou, Guo Wei
AU - Dong, Zhen Chao
AU - Huang, Jin Shun
PY - 2003
Y1 - 2003
N2 - The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) Å, V = 326.7(3) Å3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, μ = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.
AB - The title compound Ag3PSe4 was synthesized by the reaction of Ag powder, P2Se5 and Se in a molar ratio of 1:1:1 at 500°C and structurally characterized by X-ray crystallography. The crystal belongs to orthorhombic, space group Pmn21 with cell parameters: a = 7.689(4), b = 6.660(3), c = 6.379(4) Å, V = 326.7(3) Å3, Z = 2, Dc = 6.816 g/cm3, Mr = 670.42, F(000) = 584, μ = 31.302 mm-1, R = 0.0606, wR = 0.1289 and S = 1.012. The 3-D structure can be regarded as constructed from the stacking of puckered Ag-P-Se honeycomb-like sheets along the c direction, in which the Ag, P and Se atoms are bonded to each other to form a chair-like six-membered ring, and the rings then build the sheets by sharing edges.
KW - Metal chalcogenophosphide
KW - Normal tetrahedral structure
KW - Solid state reaction
UR - https://www.scopus.com/pages/publications/0038717115
M3 - Article
AN - SCOPUS:0038717115
SN - 0254-5861
VL - 22
SP - 161
EP - 164
JO - Jiegou Huaxue
JF - Jiegou Huaxue
IS - 2
ER -