Synthesis and properties of 5,5'-dinitramino-3,3'-bi[1,2,4-triazolate] carbohydrazide salt

Xiao Jun Wang; Xiao Peng Zhang; Zhi Yan Lu; Xia Wang; Shao Hua Jin; Shu Sen Chen

doi:10.11943/j.issn.1006-9941.2016.04.007

Synthesis and properties of 5,5'-dinitramino-3,3'-bi[1,2,4-triazolate] carbohydrazide salt

Xiao Jun Wang
, Xiao Peng Zhang
, Zhi Yan Lu
, Xia Wang
, Shao Hua Jin^*
, Shu Sen Chen

^*此作品的通讯作者

材料学院

Research Institute of Gansu Yinguang Chemical Industry Group
Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

5 引用（Scopus）

摘要

5,5'-Dinitramino-3, 3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT) was synthesized via ring formation reaction, nitration reaction and salt formation reaction using oxalic acid and aminoguanidinium bicarbonate as starting materials. Its structure was characterized by IR, NMR and elemental analysis. The thermal behavior of CBNT was studied by differential thermal analysis /thermogravimetry (DTA-TG) and its impact sensitivity and friction sensitivity were measured. Results show that the temperature of exothermic decomposition peak for CBNT is 229℃. Its impact sensitivity (H₅₀) is 89 cm, and friction sensitivity in explosion percentage is 4%-8%.

源语言	英语
页（从-至）	353-356
页数	4
期刊	Hanneng Cailiao/Chinese Journal of Energetic Materials
卷	24
期	4
DOI	https://doi.org/10.11943/j.issn.1006-9941.2016.04.007
出版状态	已出版 - 25 4月 2016

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title = "Synthesis and properties of 5,5'-dinitramino-3,3'-bi[1,2,4-triazolate] carbohydrazide salt",

abstract = "5,5'-Dinitramino-3, 3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT) was synthesized via ring formation reaction, nitration reaction and salt formation reaction using oxalic acid and aminoguanidinium bicarbonate as starting materials. Its structure was characterized by IR, NMR and elemental analysis. The thermal behavior of CBNT was studied by differential thermal analysis /thermogravimetry (DTA-TG) and its impact sensitivity and friction sensitivity were measured. Results show that the temperature of exothermic decomposition peak for CBNT is 229℃. Its impact sensitivity (H50) is 89 cm, and friction sensitivity in explosion percentage is 4\%-8\%.",

keywords = "5,5'-dinitramino-3,3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT), Decomposition, Energetic materials, Sensitivity, Synthesis",

author = "Wang, \{Xiao Jun\} and Zhang, \{Xiao Peng\} and Lu, \{Zhi Yan\} and Xia Wang and Jin, \{Shao Hua\} and Chen, \{Shu Sen\}",

year = "2016",

month = apr,

day = "25",

doi = "10.11943/j.issn.1006-9941.2016.04.007",

language = "English",

volume = "24",

pages = "353--356",

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TY - JOUR

T1 - Synthesis and properties of 5,5'-dinitramino-3,3'-bi[1,2,4-triazolate] carbohydrazide salt

AU - Wang, Xiao Jun

AU - Zhang, Xiao Peng

AU - Lu, Zhi Yan

AU - Wang, Xia

AU - Jin, Shao Hua

AU - Chen, Shu Sen

PY - 2016/4/25

Y1 - 2016/4/25

N2 - 5,5'-Dinitramino-3, 3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT) was synthesized via ring formation reaction, nitration reaction and salt formation reaction using oxalic acid and aminoguanidinium bicarbonate as starting materials. Its structure was characterized by IR, NMR and elemental analysis. The thermal behavior of CBNT was studied by differential thermal analysis /thermogravimetry (DTA-TG) and its impact sensitivity and friction sensitivity were measured. Results show that the temperature of exothermic decomposition peak for CBNT is 229℃. Its impact sensitivity (H50) is 89 cm, and friction sensitivity in explosion percentage is 4%-8%.

AB - 5,5'-Dinitramino-3, 3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT) was synthesized via ring formation reaction, nitration reaction and salt formation reaction using oxalic acid and aminoguanidinium bicarbonate as starting materials. Its structure was characterized by IR, NMR and elemental analysis. The thermal behavior of CBNT was studied by differential thermal analysis /thermogravimetry (DTA-TG) and its impact sensitivity and friction sensitivity were measured. Results show that the temperature of exothermic decomposition peak for CBNT is 229℃. Its impact sensitivity (H50) is 89 cm, and friction sensitivity in explosion percentage is 4%-8%.

KW - 5,5'-dinitramino-3,3'-bi[1.2.4-triazolate] carbohydrazide salt(CBNT)

KW - Decomposition

KW - Energetic materials

KW - Sensitivity

KW - Synthesis

UR - https://www.scopus.com/pages/publications/84969256472

U2 - 10.11943/j.issn.1006-9941.2016.04.007

DO - 10.11943/j.issn.1006-9941.2016.04.007

M3 - Article

AN - SCOPUS:84969256472

SN - 1006-9941

VL - 24

SP - 353

EP - 356

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 4

ER -

Synthesis and properties of 5,5'-dinitramino-3,3'-bi[1,2,4-triazolate] carbohydrazide salt

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