Synthesis and Crystal Structure of [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O Containing Mixed-valence Vanadium

Jia Ning Xu; Guo Yu Yang; Ying Jie Lin; Zhan Shi; Jie Hui Yu; Shou Hua Feng; Ji Qing Xu; Xin Xu; Yan Li; Xiao Hui Cui; Xiao Ying Huang; Lan Ping Yang

Synthesis and Crystal Structure of [N(CH₃)₄]₄ [H₅PMo₅V₉O₄₂] · 3. 5H₂O Containing Mixed-valence Vanadium

Jia Ning Xu
, Guo Yu Yang
, Ying Jie Lin
, Zhan Shi
, Jie Hui Yu
, Shou Hua Feng
, Ji Qing Xu^*
, Xin Xu
, Yan Li
, Xiao Hui Cui
, Xiao Ying Huang
, Lan Ping Yang

^*此作品的通讯作者

Jilin University
Changchun University of Science and Technology
CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

The title compound [N(CH₃)₄]₄ [H₅PMo₅V₉O₄₂] · 3. 5H₂O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1. 284 8(4) nm, b=2. 366 4(4) nm, c=2. 113 6(4) nm, β= 90. 69(2)°, V=6. 425 (4) nm³, Z=4, D_c=2. 07 g · cm^-3, R=0. 066, R_w=0. 069, S=1. 33, (Δ/σ)_max=0.04, (Δρ)_max=91 e · nm^-3.

源语言	英语
页（从-至）	1181-1182
页数	2
期刊	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
卷	21
期	8
出版状态	已出版 - 10 8月 2000
已对外发布	是

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@article{fe1b64433f5c4906a6e7d2810d37cdc2,

title = "Synthesis and Crystal Structure of [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O Containing Mixed-valence Vanadium",

abstract = "The title compound [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1. 284 8(4) nm, b=2. 366 4(4) nm, c=2. 113 6(4) nm, β= 90. 69(2)°, V=6. 425 (4) nm3, Z=4, Dc=2. 07 g · cm-3, R=0. 066, Rw=0. 069, S=1. 33, (Δ/σ)max=0.04, (Δρ)max=91 e · nm-3.",

keywords = "Crystal structure, Hydrothermal synthesis, Mixed valence",

author = "Xu, \{Jia Ning\} and Yang, \{Guo Yu\} and Lin, \{Ying Jie\} and Zhan Shi and Yu, \{Jie Hui\} and Feng, \{Shou Hua\} and Xu, \{Ji Qing\} and Xin Xu and Yan Li and Cui, \{Xiao Hui\} and Huang, \{Xiao Ying\} and Yang, \{Lan Ping\}",

year = "2000",

month = aug,

day = "10",

language = "English",

volume = "21",

pages = "1181--1182",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "8",

}

TY - JOUR

T1 - Synthesis and Crystal Structure of [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O Containing Mixed-valence Vanadium

AU - Xu, Jia Ning

AU - Yang, Guo Yu

AU - Lin, Ying Jie

AU - Shi, Zhan

AU - Yu, Jie Hui

AU - Feng, Shou Hua

AU - Xu, Ji Qing

AU - Xu, Xin

AU - Li, Yan

AU - Cui, Xiao Hui

AU - Huang, Xiao Ying

AU - Yang, Lan Ping

PY - 2000/8/10

Y1 - 2000/8/10

N2 - The title compound [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1. 284 8(4) nm, b=2. 366 4(4) nm, c=2. 113 6(4) nm, β= 90. 69(2)°, V=6. 425 (4) nm3, Z=4, Dc=2. 07 g · cm-3, R=0. 066, Rw=0. 069, S=1. 33, (Δ/σ)max=0.04, (Δρ)max=91 e · nm-3.

AB - The title compound [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is a bicapped Keggin polyanion, two vanadium atoms are distributed at two capping metal atom positions. The crystal is monoclinic, space group C2/c with a=1. 284 8(4) nm, b=2. 366 4(4) nm, c=2. 113 6(4) nm, β= 90. 69(2)°, V=6. 425 (4) nm3, Z=4, Dc=2. 07 g · cm-3, R=0. 066, Rw=0. 069, S=1. 33, (Δ/σ)max=0.04, (Δρ)max=91 e · nm-3.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Mixed valence

UR - https://www.scopus.com/pages/publications/0346387084

M3 - Article

AN - SCOPUS:0346387084

SN - 0251-0790

VL - 21

SP - 1181

EP - 1182

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 8

ER -

Synthesis and Crystal Structure of [N(CH3)4]4 [H5PMo5V9O42] · 3. 5H2O Containing Mixed-valence Vanadium

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Synthesis and Crystal Structure of [N(CH₃)₄]₄ [H₅PMo₅V₉O₄₂] · 3. 5H₂O Containing Mixed-valence Vanadium