TY - JOUR
T1 - Synthesis and characterization of Ga2(phen)(HPO4 )3
T2 - A new 2D hybrid gallium phosphate with neutral framework
AU - Lin, Zhi En
AU - Zhang, Jie
AU - Zheng, Shou Tian
AU - Yang, Guo Yu
PY - 2004/7/8
Y1 - 2004/7/8
N2 - A new layered inorganic-organic hybrid gallium phosphate, Ga2 (phen)(HPO4)3 (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) Å, b=11.7968(10) Å, c=12.1458(9) Å, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) Å3, Z=2. The structure is built from strictly alternating GaO4N2 octahedra, GaO4 tetrahedra and HPO4 tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.
AB - A new layered inorganic-organic hybrid gallium phosphate, Ga2 (phen)(HPO4)3 (phen=1,10-phenanthroline), has been hydrothermally synthesized and characterized by single crystal X-ray diffraction, FTIR, elemental analysis, ICP, power X-ray diffraction and thermogravimetric analysis. This compound crystallizes in the triclinic system, space group P-1 (No. 2), a=7.7730(6) Å, b=11.7968(10) Å, c=12.1458(9) Å, α=114.089(2)°, β=102.310(2) °, γ=102.905(2)°, V=931.28(13) Å3, Z=2. The structure is built from strictly alternating GaO4N2 octahedra, GaO4 tetrahedra and HPO4 tetrahedra through their vertices, forming a neutral layered architecture grafted with phen ligands. The adjacent sheets are stacked in an AAAA sequence along [0 0 1] direction and held together by strong π-π interactions.
KW - Crystal structure
KW - Gallium phosphate
KW - Hybrid solid
KW - Hydrothermal synthesis
KW - Layer
UR - https://www.scopus.com/pages/publications/2942709484
U2 - 10.1016/j.micromeso.2004.04.016
DO - 10.1016/j.micromeso.2004.04.016
M3 - Article
AN - SCOPUS:2942709484
SN - 1387-1811
VL - 72
SP - 43
EP - 47
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
IS - 1-3
ER -