Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

Pengfei Hao; Zhi Yang; Xiaoli Ma; Xiujuan Wang; Zhihong Liu; Herbert W. Roesky; Kening Sun; Jiarong Li; Mingdong Zhong

doi:10.1039/c2dt31872e

Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

Pengfei Hao
, Zhi Yang^*
, Xiaoli Ma
, Xiujuan Wang
, Zhihong Liu
, Herbert W. Roesky
, Kening Sun
, Jiarong Li
, Mingdong Zhong

^*此作品的通讯作者

Beijing Institute of Technology
University of Göttingen

科研成果: 期刊稿件 › 文章 › 同行评审

28 引用（Scopus）

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The reactions of LAlH₂ (L = HC(CMeNAr)₂, Ar = 2,6-iPr₂C₆H₃) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)] ₂Si(Ph)₂ (2), [LAl(μ-O)]₂PO(Ph) (3), LAl[OPO(Ph)₂]₂ (4), and LAl(μ-O)₂(o-C ₆H₄) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(μ-O)]₂P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.

源语言	英语
页（从-至）	13520-13524
页数	5
期刊	Dalton Transactions
卷	41
期	43
DOI	https://doi.org/10.1039/c2dt31872e
出版状态	已出版 - 21 11月 2012
已对外发布	是

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@article{60fccacb46474b0b97c2292295f9ec98,

title = "Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif",

abstract = "The reactions of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)] 2Si(Ph)2 (2), [LAl(μ-O)]2PO(Ph) (3), LAl[OPO(Ph)2]2 (4), and LAl(μ-O)2(o-C 6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(μ-O)]2P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.",

author = "Pengfei Hao and Zhi Yang and Xiaoli Ma and Xiujuan Wang and Zhihong Liu and Roesky, \{Herbert W.\} and Kening Sun and Jiarong Li and Mingdong Zhong",

year = "2012",

month = nov,

day = "21",

doi = "10.1039/c2dt31872e",

language = "English",

volume = "41",

pages = "13520--13524",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "43",

}

TY - JOUR

T1 - Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

AU - Hao, Pengfei

AU - Yang, Zhi

AU - Ma, Xiaoli

AU - Wang, Xiujuan

AU - Liu, Zhihong

AU - Roesky, Herbert W.

AU - Sun, Kening

AU - Li, Jiarong

AU - Zhong, Mingdong

PY - 2012/11/21

Y1 - 2012/11/21

N2 - The reactions of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)] 2Si(Ph)2 (2), [LAl(μ-O)]2PO(Ph) (3), LAl[OPO(Ph)2]2 (4), and LAl(μ-O)2(o-C 6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(μ-O)]2P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.

AB - The reactions of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)] 2Si(Ph)2 (2), [LAl(μ-O)]2PO(Ph) (3), LAl[OPO(Ph)2]2 (4), and LAl(μ-O)2(o-C 6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(μ-O)]2P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.

UR - https://www.scopus.com/pages/publications/84867500142

U2 - 10.1039/c2dt31872e

DO - 10.1039/c2dt31872e

M3 - Article

AN - SCOPUS:84867500142

SN - 1477-9226

VL - 41

SP - 13520

EP - 13524

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

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