TY - JOUR
T1 - Synthesis and characterization of a new hybrid zinc phosphite (4,4′-bipy)[Zn(HPO3)]2 with a pillared layer structure
AU - Lin, Zhi En
AU - Zhang, Jie
AU - Zheng, Shou Tian
AU - Yang, G. Y.Guo Yu
PY - 2004/3/8
Y1 - 2004/3/8
N2 - A new inorganic-organic hybrid solid, (4,4′-bipy) [Zn(HPO3)]2 (4,4′-bipy= 4,4′-bipyridine), has been hydrothermally synthesized in the presence of 4,4′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P21/c, with a=9.741(2), b=7.4423(16), c=10.271(2) Å, β=100.038(4)°, V=733.3(3) Å3, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.
AB - A new inorganic-organic hybrid solid, (4,4′-bipy) [Zn(HPO3)]2 (4,4′-bipy= 4,4′-bipyridine), has been hydrothermally synthesized in the presence of 4,4′-bipy ligand. Its structure was determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, ICP analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectrum. It crystallized in the monoclinic space group, P21/c, with a=9.741(2), b=7.4423(16), c=10.271(2) Å, β=100.038(4)°, V=733.3(3) Å3, Z=2. The structure consists of neutral sheets of zinc phosphite which is pillared through 4,4′-bipy ligands to generate a 3D framework. The compound shows relatively high thermal stability and exhibits intense photoluminescence upon photo-excitation at 362 nm.
KW - Crystal structure
KW - Fluorescent emission
KW - Hybrid solid
KW - Open-framework
KW - Zinc phosphite
UR - https://www.scopus.com/pages/publications/1442359025
U2 - 10.1016/j.micromeso.2003.11.015
DO - 10.1016/j.micromeso.2003.11.015
M3 - Article
AN - SCOPUS:1442359025
SN - 1387-1811
VL - 68
SP - 65
EP - 70
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
IS - 1-3
ER -