Synthesis and characterization of a 1D chain-like Cu6 substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes

Yan Ying Li; Jun Wei Zhao; Qi Wei; Bai Feng Yang; Guo Yu Yang

doi:10.1016/j.jssc.2013.11.019

Synthesis and characterization of a 1D chain-like Cu₆ substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes

Yan Ying Li
, Jun Wei Zhao^*
, Qi Wei
, Bai Feng Yang
, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

A novel Cu-azido complex modified hexa-Cu^II substituted sandwich-type phosphotungstate [Cu(en)₂]{[Cu₂(en) ₂(μ-1,1-N₃)₂(H₂O)] ₂[Cu₆(en)₂(H₂O)₂(B- α-PW₉O₃₄)₂]}·6H₂O (1) (en=ethylene-diamine) has been prepared under hydrothermal conditions and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 displays a beautiful 1-D chain architecture constructed from sandwich-type [Cu₂(en) ₂(μ-1,1-N₃)₂(H₂O)] ₂[Cu₆(en)₂(H₂O)₂(B- α-PW₉O₃₄)₂]^2- units and [Cu(en)₂]²⁺ linkers. To our knowledge, 1 represents the first hexa-Cu^II sandwiched phosphotungstate with supporting Cu-azido complexes.

源语言	英语
页（从-至）	166-170
页数	5
期刊	Journal of Solid State Chemistry
卷	210
期	1
DOI	https://doi.org/10.1016/j.jssc.2013.11.019
出版状态	已出版 - 2月 2014

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10.1016/j.jssc.2013.11.019

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@article{5098506a01234924af1d4e9c1d5938f3,

title = "Synthesis and characterization of a 1D chain-like Cu6 substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes",

abstract = "A novel Cu-azido complex modified hexa-CuII substituted sandwich-type phosphotungstate [Cu(en)2]\{[Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]\}·6H2O (1) (en=ethylene-diamine) has been prepared under hydrothermal conditions and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 displays a beautiful 1-D chain architecture constructed from sandwich-type [Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]2- units and [Cu(en)2]2+ linkers. To our knowledge, 1 represents the first hexa-CuII sandwiched phosphotungstate with supporting Cu-azido complexes.",

keywords = "Azido, Phosphotungstate",

author = "Li, \{Yan Ying\} and Zhao, \{Jun Wei\} and Qi Wei and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

year = "2014",

month = feb,

doi = "10.1016/j.jssc.2013.11.019",

language = "English",

volume = "210",

pages = "166--170",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of a 1D chain-like Cu6 substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes

AU - Li, Yan Ying

AU - Zhao, Jun Wei

AU - Wei, Qi

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2014/2

Y1 - 2014/2

N2 - A novel Cu-azido complex modified hexa-CuII substituted sandwich-type phosphotungstate [Cu(en)2]{[Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]}·6H2O (1) (en=ethylene-diamine) has been prepared under hydrothermal conditions and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 displays a beautiful 1-D chain architecture constructed from sandwich-type [Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]2- units and [Cu(en)2]2+ linkers. To our knowledge, 1 represents the first hexa-CuII sandwiched phosphotungstate with supporting Cu-azido complexes.

AB - A novel Cu-azido complex modified hexa-CuII substituted sandwich-type phosphotungstate [Cu(en)2]{[Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]}·6H2O (1) (en=ethylene-diamine) has been prepared under hydrothermal conditions and structurally characterized by elemental analyses, IR spectra, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. 1 displays a beautiful 1-D chain architecture constructed from sandwich-type [Cu2(en) 2(μ-1,1-N3)2(H2O)] 2[Cu6(en)2(H2O)2(B- α-PW9O34)2]2- units and [Cu(en)2]2+ linkers. To our knowledge, 1 represents the first hexa-CuII sandwiched phosphotungstate with supporting Cu-azido complexes.

KW - Azido

KW - Phosphotungstate

UR - https://www.scopus.com/pages/publications/84891082304

U2 - 10.1016/j.jssc.2013.11.019

DO - 10.1016/j.jssc.2013.11.019

M3 - Article

AN - SCOPUS:84891082304

SN - 0022-4596

VL - 210

SP - 166

EP - 170

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 1

ER -

Synthesis and characterization of a 1D chain-like Cu6 substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes

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Synthesis and characterization of a 1D chain-like Cu₆ substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes