Syntheses and characterization of two new zinc phosphites with 1D chains decorated by Zn-centered complexes

You Ju Zhong; Yong Mei Chen; Yan Qiong Sun; Guo Yu Yang

doi:10.1016/j.jssc.2005.05.028

Syntheses and characterization of two new zinc phosphites with 1D chains decorated by Zn-centered complexes

You Ju Zhong
, Yong Mei Chen
, Yan Qiong Sun
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Beijing University of Chemical Technology

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

Two inorganic-organic hybrid solids, Zn₂(phen)(HPO ₃)₂ (1) and Zn(phen)(HPO₃) (2), have been synthesized under solvothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectra. Compound 1 crystallizes in the triclnic system, space group P-1, a=8.1813(3)Å, b=8.5535(3)Å, c=12.3031(5)Å, α=75.609(1)°, β=79.145(2)°, γ=67.157(2)°, V=764.46(5)Å3, Z=2. Compound 2 is monoclinic, C2/c, a=16.1044(7)Å, b=18.9447(6)Å, c=8.1713(6)Å, β=94.175(4)°, V=2486.4(2)Å3, Z=8. Both structures consist of 1D chains constructed from strictly alternating ZnO ₄ and HPO₃ polyhedra through sharing vertices. The chains are further decorated by Zn-centered complex architectures, [Zn(phen)] ²⁺ for 1 and [Zn(phen)₂]²⁺ for 2. The 2D and 3D supramolecular arrays for 1 and 2 are stably stacked via strong π-π interactions of the phen groups, respectively.

源语言	英语
页（从-至）	2613-2619
页数	7
期刊	Journal of Solid State Chemistry
卷	178
期	9
DOI	https://doi.org/10.1016/j.jssc.2005.05.028
出版状态	已出版 - 9月 2005
已对外发布	是

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10.1016/j.jssc.2005.05.028

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@article{c73ab57b9d57460ca6d774a9fb541ab3,

title = "Syntheses and characterization of two new zinc phosphites with 1D chains decorated by Zn-centered complexes",

abstract = "Two inorganic-organic hybrid solids, Zn2(phen)(HPO 3)2 (1) and Zn(phen)(HPO3) (2), have been synthesized under solvothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectra. Compound 1 crystallizes in the triclnic system, space group P-1, a=8.1813(3){\AA}, b=8.5535(3){\AA}, c=12.3031(5){\AA}, α=75.609(1)°, β=79.145(2)°, γ=67.157(2)°, V=764.46(5){\AA}3, Z=2. Compound 2 is monoclinic, C2/c, a=16.1044(7){\AA}, b=18.9447(6){\AA}, c=8.1713(6){\AA}, β=94.175(4)°, V=2486.4(2){\AA}3, Z=8. Both structures consist of 1D chains constructed from strictly alternating ZnO 4 and HPO3 polyhedra through sharing vertices. The chains are further decorated by Zn-centered complex architectures, [Zn(phen)] 2+ for 1 and [Zn(phen)2]2+ for 2. The 2D and 3D supramolecular arrays for 1 and 2 are stably stacked via strong π-π interactions of the phen groups, respectively.",

keywords = "1,10-phenanthroline, Crystal structure, Hydrothermal synthesis, Zinc phosphite",

author = "Zhong, \{You Ju\} and Chen, \{Yong Mei\} and Sun, \{Yan Qiong\} and Yang, \{Guo Yu\}",

year = "2005",

month = sep,

doi = "10.1016/j.jssc.2005.05.028",

language = "English",

volume = "178",

pages = "2613--2619",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "9",

}

TY - JOUR

T1 - Syntheses and characterization of two new zinc phosphites with 1D chains decorated by Zn-centered complexes

AU - Zhong, You Ju

AU - Chen, Yong Mei

AU - Sun, Yan Qiong

AU - Yang, Guo Yu

PY - 2005/9

Y1 - 2005/9

N2 - Two inorganic-organic hybrid solids, Zn2(phen)(HPO 3)2 (1) and Zn(phen)(HPO3) (2), have been synthesized under solvothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectra. Compound 1 crystallizes in the triclnic system, space group P-1, a=8.1813(3)Å, b=8.5535(3)Å, c=12.3031(5)Å, α=75.609(1)°, β=79.145(2)°, γ=67.157(2)°, V=764.46(5)Å3, Z=2. Compound 2 is monoclinic, C2/c, a=16.1044(7)Å, b=18.9447(6)Å, c=8.1713(6)Å, β=94.175(4)°, V=2486.4(2)Å3, Z=8. Both structures consist of 1D chains constructed from strictly alternating ZnO 4 and HPO3 polyhedra through sharing vertices. The chains are further decorated by Zn-centered complex architectures, [Zn(phen)] 2+ for 1 and [Zn(phen)2]2+ for 2. The 2D and 3D supramolecular arrays for 1 and 2 are stably stacked via strong π-π interactions of the phen groups, respectively.

AB - Two inorganic-organic hybrid solids, Zn2(phen)(HPO 3)2 (1) and Zn(phen)(HPO3) (2), have been synthesized under solvothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. Their structures were determined by single-crystal X-ray diffraction and further characterized by FTIR, elemental analysis, powder X-ray diffraction, thermogravimetric analysis and fluorescent spectra. Compound 1 crystallizes in the triclnic system, space group P-1, a=8.1813(3)Å, b=8.5535(3)Å, c=12.3031(5)Å, α=75.609(1)°, β=79.145(2)°, γ=67.157(2)°, V=764.46(5)Å3, Z=2. Compound 2 is monoclinic, C2/c, a=16.1044(7)Å, b=18.9447(6)Å, c=8.1713(6)Å, β=94.175(4)°, V=2486.4(2)Å3, Z=8. Both structures consist of 1D chains constructed from strictly alternating ZnO 4 and HPO3 polyhedra through sharing vertices. The chains are further decorated by Zn-centered complex architectures, [Zn(phen)] 2+ for 1 and [Zn(phen)2]2+ for 2. The 2D and 3D supramolecular arrays for 1 and 2 are stably stacked via strong π-π interactions of the phen groups, respectively.

KW - 1,10-phenanthroline

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Zinc phosphite

UR - https://www.scopus.com/pages/publications/24144487458

U2 - 10.1016/j.jssc.2005.05.028

DO - 10.1016/j.jssc.2005.05.028

M3 - Article

AN - SCOPUS:24144487458

SN - 0022-4596

VL - 178

SP - 2613

EP - 2619

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 9

ER -

Syntheses and characterization of two new zinc phosphites with 1D chains decorated by Zn-centered complexes

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