Study on synthesis of N-propargyl-R-2-heptylamine

Lin Yang; Yu Lin Deng; Rong Ji Dai; Wei Liu

Study on synthesis of N-propargyl-R-2-heptylamine

Lin Yang^*
, Yu Lin Deng
, Rong Ji Dai
, Wei Liu

^*此作品的通讯作者

Beijing Institute of Technology
China National Chemical Corporation

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

源语言	英语
页（从-至）	44-46+48
期刊	Xiandai Huagong/Modern Chemical Industry
卷	28
期	10
出版状态	已出版 - 10月 2008

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title = "Study on synthesis of N-propargyl-R-2-heptylamine",

abstract = "A kind of 2-heptylamine is prepared in a yield of 76.8\% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4\%. N-propargyl-R-2-heptylamine is synthesized in an 82.2\% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.",

keywords = "N-propargyl-R-2-heptylamine, R-2-heptylamine, Resolution, Synthesis",

author = "Lin Yang and Deng, \{Yu Lin\} and Dai, \{Rong Ji\} and Wei Liu",

year = "2008",

month = oct,

language = "English",

volume = "28",

pages = "44--46+48",

journal = "Xiandai Huagong/Modern Chemical Industry",

issn = "0253-4320",

publisher = "China National Chemical Information Center",

number = "10",

}

TY - JOUR

T1 - Study on synthesis of N-propargyl-R-2-heptylamine

AU - Yang, Lin

AU - Deng, Yu Lin

AU - Dai, Rong Ji

AU - Liu, Wei

PY - 2008/10

Y1 - 2008/10

N2 - A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

AB - A kind of 2-heptylamine is prepared in a yield of 76.8% from 2-oenanthone and ammonium formate. Through the resolution of racemic 2-heptylamine by D-dibenzoyltartaric acid with the yield of 41.4%. N-propargyl-R-2-heptylamine is synthesized in an 82.2% yield from R-2-heptylamine, acetylene and formaldehyde with copper iodide as the catalyst. The possible reaction mechanisms are also approached.

KW - N-propargyl-R-2-heptylamine

KW - R-2-heptylamine

KW - Resolution

KW - Synthesis

UR - https://www.scopus.com/pages/publications/55949099646

M3 - Article

AN - SCOPUS:55949099646

SN - 0253-4320

VL - 28

SP - 44-46+48

JO - Xiandai Huagong/Modern Chemical Industry

JF - Xiandai Huagong/Modern Chemical Industry

IS - 10

ER -

Study on synthesis of N-propargyl-R-2-heptylamine

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