@inproceedings{370def666ce741a18a51461a51404dc2,
title = "Study on Synthesis and Characterization of Bipyridine Ligated Scandium Complex ((C20H30N2)Sc(CH2SiMe3)3(THF)) and Its Catalytic Performance in Polymerization of Polar Conjugated Dienes",
abstract = "The highly cis-1,4 functionalized polyconjugated dienes was prepared by high-position/stereoregular coordination polymerization of poly(conjugated dienes)s can effectively introduce a number of heteroatom groups into synthetic rubbers, but it cannot only effectively improve the performance of synthetic rubber, but also develop new functional polyconjugated diene materials to broaden its application range. However, the rare earth metal catalysts that can promote the coordination polymerization of polar conjugated diene monomers are currently very limited. The bipyridine complex ((C20H30N2)Sc(CH2SiMe3)3(THF)) was simply synthesized using bipyridyl derivative ligand and equal amounts of Sc(CH2SiMe3)3(THF)2. For the bipyridyl-scandium trialkyl complex, different feeding ratios of cocatalyst borate can produce different catalytically active species. These generated catalytically active species can achieve coordination polymerization of polar 2-(2-methoxyphenyl)-1,3-butadiene.",
keywords = "polar conjugated dienes, position/stereoselectivity, scandium catalyst",
author = "Qiaozhen Li and Mingqi Wang and Xiaofang Li",
note = "Publisher Copyright: {\textcopyright} 2023 SPIE. All rights reserved.; 4th International Conference on Optoelectronic Science and Materials, ICOSM 2022 ; Conference date: 16-09-2022 Through 18-09-2022",
year = "2023",
doi = "10.1117/12.2667273",
language = "English",
series = "Proceedings of SPIE - The International Society for Optical Engineering",
publisher = "SPIE",
editor = "Yuan Lu",
booktitle = "Fourth International Conference on Optoelectronic Science and Materials, ICOSM 2022",
address = "United States",
}