Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions

Yuan Deng; Ting Zhen Ding; Yong Li

doi:10.1081/SIM-120003204

Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions

Yuan Deng^*
, Ting Zhen Ding
, Yong Li

^*此作品的通讯作者

Tsinghua University

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

A series of new complexes, [HB{pz^An}₃]CuOAc (1), [HB{pz^An}₃]CuCl(pz^AnH) (2), ([HB{pz^An,Me}₃]Cu)₂OAc (3) and [HB{pz^An,Me}₃]CuCl(pz^An,MeH) (4) [pz^An = 3-(p-anisyl)pyrazolyl, pz^An,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands v_as(CO₂) and v_s(CO₂) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).

源语言	英语
页（从-至）	219-229
页数	11
期刊	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
卷	32
期	2
DOI	https://doi.org/10.1081/SIM-120003204
出版状态	已出版 - 2002
已对外发布	是

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title = "Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions",

abstract = "A series of new complexes, [HB\{pzAn\}3]CuOAc (1), [HB\{pzAn\}3]CuCl(pzAnH) (2), ([HB\{pzAn,Me\}3]Cu)2OAc (3) and [HB\{pzAn,Me\}3]CuCl(pzAn,MeH) (4) [pzAn = 3-(p-anisyl)pyrazolyl, pzAn,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands vas(CO2) and vs(CO2) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).",

author = "Yuan Deng and Ding, \{Ting Zhen\} and Yong Li",

year = "2002",

doi = "10.1081/SIM-120003204",

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TY - JOUR

T1 - Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions

AU - Deng, Yuan

AU - Ding, Ting Zhen

AU - Li, Yong

PY - 2002

Y1 - 2002

N2 - A series of new complexes, [HB{pzAn}3]CuOAc (1), [HB{pzAn}3]CuCl(pzAnH) (2), ([HB{pzAn,Me}3]Cu)2OAc (3) and [HB{pzAn,Me}3]CuCl(pzAn,MeH) (4) [pzAn = 3-(p-anisyl)pyrazolyl, pzAn,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands vas(CO2) and vs(CO2) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).

AB - A series of new complexes, [HB{pzAn}3]CuOAc (1), [HB{pzAn}3]CuCl(pzAnH) (2), ([HB{pzAn,Me}3]Cu)2OAc (3) and [HB{pzAn,Me}3]CuCl(pzAn,MeH) (4) [pzAn = 3-(p-anisyl)pyrazolyl, pzAn,Me = 3-(p-anisyl)-5-methylpyrazolyl] have been synthesized and characterized by elemental analyses, IR spectra, ESR spectra, mass spectra and CV measurements. The compounds (2) and (4) are five-coordinated with an additional pyrazole ligand. The infrared bands vas(CO2) and vs(CO2) indicate that the acetate is an unidentate ligand in (1) but a bridging one in (3).

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DO - 10.1081/SIM-120003204

M3 - Article

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SN - 0094-5714

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EP - 229

JO - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

JF - Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

IS - 2

ER -

Studies of the coordination chemistry of pyrazolylborate derivatives with copper(II) ions

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