Structure, thermodynamics and sensitivity property of (TAGH)CIO₄

Triaminoguandine Perchlorate was synthesized with triaminoguandine and perchloric acid as primary materials. The crystal structure was determined by X-ray single crystal diffraction analysis. The results show that the title compound belongs to monoclinic system with P2(1)/c space group and cell parameters of a=1. 021 3(11) nm,b=1. 486 9(15)nm,c=l. 093 6(11)nm,β=102. 91(2)°. The title compound,with formula of CH₉ClN ₆O₄, is an ionic compound formed by [C(N₂H ₃)₃]⁺ and ClO₄^-. There are a lot of intramolecular and intermolecular hydrogen bonds, which make it stable. The title compound was characterized by elemental analysis, FTIR, DSC, TG-DTG. The results show that the title compound lost 99. 7% at 457. 03°C with a heating rate of 10°C/min. The sensitivity test results show that it has low friction sensitivity and has no frame sensitivity and impact sensitivity under the sensitivity test conditions.