Stabilization of Grignard reagents by a pillar[5]arene host-Schlenk equilibria and Grignard reactions

Lingyi Shen; Yanxia Zhao; Dihua Dai; Ying Wei Yang; Biao Wu; Xiao Juan Yang

doi:10.1039/c9cc08728a

Stabilization of Grignard reagents by a pillar[5]arene host-Schlenk equilibria and Grignard reactions

Lingyi Shen
, Yanxia Zhao
, Dihua Dai
, Ying Wei Yang^*
, Biao Wu
, Xiao Juan Yang

^*此作品的通讯作者

Northwest University China
Jilin University
Lanzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

16 引用（Scopus）

摘要

Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.

源语言	英语
页（从-至）	1381-1384
页数	4
期刊	Chemical Communications
卷	56
期	9
DOI	https://doi.org/10.1039/c9cc08728a
出版状态	已出版 - 2020
已对外发布	是

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10.1039/c9cc08728a

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title = "Stabilization of Grignard reagents by a pillar[5]arene host-Schlenk equilibria and Grignard reactions",

abstract = "Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.",

author = "Lingyi Shen and Yanxia Zhao and Dihua Dai and Yang, \{Ying Wei\} and Biao Wu and Yang, \{Xiao Juan\}",

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AU - Shen, Lingyi

AU - Zhao, Yanxia

AU - Dai, Dihua

AU - Yang, Ying Wei

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2020

Y1 - 2020

N2 - Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.

AB - Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.

UR - https://www.scopus.com/pages/publications/85078693760

U2 - 10.1039/c9cc08728a

DO - 10.1039/c9cc08728a

M3 - Article

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AN - SCOPUS:85078693760

SN - 1359-7345

VL - 56

SP - 1381

EP - 1384

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Stabilization of Grignard reagents by a pillar[5]arene host-Schlenk equilibria and Grignard reactions

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