Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

Ya Nan Dong; Jin Peng Xue; Meng Yu; Jun Tao

doi:10.1016/j.inoche.2022.109475

Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

Ya Nan Dong
, Jin Peng Xue
, Meng Yu^*
, Jun Tao

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

6 引用（Scopus）

摘要

A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)₂] in methanol, i.e. trans-[Fe₂(pyrtrz)₅(NCS)₄]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

源语言	英语
文章编号	109475
期刊	Inorganic Chemistry Communications
卷	140
DOI	https://doi.org/10.1016/j.inoche.2022.109475
出版状态	已出版 - 6月 2022

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@article{4b3917b67059463daca1db984b2d2b66,

title = "Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure",

abstract = "A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.",

keywords = "4-substituted triazole ligand, Dinuclear complex, Polymorphism, Spin crossover",

author = "Dong, \{Ya Nan\} and Xue, \{Jin Peng\} and Meng Yu and Jun Tao",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2022",

month = jun,

doi = "10.1016/j.inoche.2022.109475",

language = "English",

volume = "140",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

AU - Dong, Ya Nan

AU - Xue, Jin Peng

AU - Yu, Meng

AU - Tao, Jun

PY - 2022/6

Y1 - 2022/6

N2 - A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

AB - A trans-isomeric dinuclear complex is synthesized by reacting ligand 4-((1H-pyrrol-2-yl)methylene-amino)-4H-1,2,4-triazole (pyrtrz) with [Fe(NCS)2] in methanol, i.e. trans-[Fe2(pyrtrz)5(NCS)4]·7MeOH (trans-1·7MeOH), which shows complete spin-crossover behaviour from the structural point of view and incomplete spin crossover due to the partial loss of guest solvent molecules.

KW - 4-substituted triazole ligand

KW - Dinuclear complex

KW - Polymorphism

KW - Spin crossover

UR - https://www.scopus.com/pages/publications/85129263587

U2 - 10.1016/j.inoche.2022.109475

DO - 10.1016/j.inoche.2022.109475

M3 - Article

AN - SCOPUS:85129263587

SN - 1387-7003

VL - 140

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

M1 - 109475

ER -

Spin crossover of a dinuclear Fe(II) complex in the trans-isomeric structure

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