Spin-active metallofullerene stabilized by the core of an nc moiety

Yongqiang Feng; Taishan Wang; Jingyi Wu; Yihan Ma; Zhuxia Zhang; Li Jiang; Chunhua Ge; Chunying Shu; Chunru Wang

doi:10.1039/c3cc38445d

Spin-active metallofullerene stabilized by the core of an nc moiety

Yongqiang Feng
, Taishan Wang^*
, Jingyi Wu
, Yihan Ma
, Zhuxia Zhang
, Li Jiang
, Chunhua Ge
, Chunying Shu
, Chunru Wang

^*此作品的通讯作者

CAS - Institute of Chemistry
CAS - Institute of High Energy Physics
Liaoning University

科研成果: 期刊稿件 › 文章 › 同行评审

22 引用（Scopus）

摘要

A paramagnetic Sc₃NC@C₈₀ anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

源语言	英语
页（从-至）	2148-2150
页数	3
期刊	Chemical Communications
卷	49
期	21
DOI	https://doi.org/10.1039/c3cc38445d
出版状态	已出版 - 14 2月 2013
已对外发布	是

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10.1039/c3cc38445d

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title = "Spin-active metallofullerene stabilized by the core of an nc moiety",

abstract = "A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.",

author = "Yongqiang Feng and Taishan Wang and Jingyi Wu and Yihan Ma and Zhuxia Zhang and Li Jiang and Chunhua Ge and Chunying Shu and Chunru Wang",

year = "2013",

month = feb,

day = "14",

doi = "10.1039/c3cc38445d",

language = "English",

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pages = "2148--2150",

journal = "Chemical Communications",

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T1 - Spin-active metallofullerene stabilized by the core of an nc moiety

AU - Feng, Yongqiang

AU - Wang, Taishan

AU - Wu, Jingyi

AU - Ma, Yihan

AU - Zhang, Zhuxia

AU - Jiang, Li

AU - Ge, Chunhua

AU - Shu, Chunying

AU - Wang, Chunru

PY - 2013/2/14

Y1 - 2013/2/14

N2 - A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

AB - A paramagnetic Sc3NC@C80 anion radical was obtained by chemical reduction. ESR spectrometry and theoretical calculations disclosed that the core NC moiety takes possession of the unpaired electron and stabilizes the paramagnetic species. It is the first time a paramagnetic metal cyanide metallofullerene has been obtained.

UR - https://www.scopus.com/pages/publications/84874059510

U2 - 10.1039/c3cc38445d

DO - 10.1039/c3cc38445d

M3 - Article

AN - SCOPUS:84874059510

SN - 1359-7345

VL - 49

SP - 2148

EP - 2150

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Spin-active metallofullerene stabilized by the core of an nc moiety

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