Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

Chun Ding Zhou; Chao Chen; Li Xuan Cai; Jie Zhang

doi:10.1039/c2dt12260j

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

Chun Ding Zhou
, Chao Chen
, Li Xuan Cai
, Jie Zhang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

A one-dimensional iron(ii) coordination polymer, [Fe ₃(hpdc) ₂(H ₂O) ₆]·2H ₂O (H ₃hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

源语言	英语
页（从-至）	5912-5918
页数	7
期刊	Dalton Transactions
卷	41
期	19
DOI	https://doi.org/10.1039/c2dt12260j
出版状态	已出版 - 21 5月 2012
已对外发布	是

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title = "Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition",

abstract = "A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.",

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T1 - Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

AU - Zhou, Chun Ding

AU - Chen, Chao

AU - Cai, Li Xuan

AU - Zhang, Jie

PY - 2012/5/21

Y1 - 2012/5/21

N2 - A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

AB - A one-dimensional iron(ii) coordination polymer, [Fe 3(hpdc) 2(H 2O) 6]·2H 2O (H 3hpdc = 2-hydroxypyrimidine-4,6-dicarboxylic acid) has been synthesized and characterized. The compound exhibits field-induced two-step magnetic phase transitions and a coexistence of spin-canting and metamagnetism, and undergoes a structural transformation from single-crystalline to amorphous state upon dehydration, accompanied by significantly enhanced spontaneous magnetization and critical temperature.

UR - https://www.scopus.com/pages/publications/84860381636

U2 - 10.1039/c2dt12260j

DO - 10.1039/c2dt12260j

M3 - Article

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VL - 41

SP - 5912

EP - 5918

JO - Dalton Transactions

JF - Dalton Transactions

IS - 19

ER -

Solvent-modulated metamagnetism in an Fe(ii) system exhibiting a two-step field-induced magnetic transition

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