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Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model

  • Miyi Li
  • , Dana Constantinescu
  • , Lisheng Wang
  • , André Mohs
  • , Juürgen Gmehling*
  • *此作品的通讯作者
  • Beijing Institute of Technology
  • Institut Fuür Reine und Angewandte Chemie

科研成果: 期刊稿件文章同行评审

摘要

The solubilities of NaCl, KCl, LiCl, and LiBr in pure methanol, ethanol, and acetone were measured over a temperature range from 293.15 to 333.15 K. Furthermore salt solubilities in the mixed solvents (water + methanol, water + ethanol, water + acetone, methanol + ethanol, methanol + acetone, ethanol + acetone) were determined at 313.15 K. For a few systems solubility data are reported for the first time. In a few cases a comparison with published data stored in the Dortmund Data Bank (DDB)(1)showed disagreement. The LIQUAC model was used to correlate the experimental data. The calculated salt solubilities are in good agreement with the experimental results for the systems NaCl + water + methanol and KCl + water + methanol.

源语言英语
页(从-至)4981-4988
页数8
期刊Industrial and Engineering Chemistry Research
49
10
DOI
出版状态已出版 - 19 5月 2010
已对外发布

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