摘要
It is vital to construct luminescent single-molecule magnets (SMMs) and explore their applications in quantum computing technique and magneto-luminescence devices. In this work, we report a luminescent single-molecule magnet with thermally activated delayed fluorescence (TADF) based on metallofullerene DyY2N@C80. DyY2N@C80 was constructed by integrating dysprosium and yttrium ions into a fullerene cage. Magnetic results suggest that DyY2N@C80 exhibits magnetic hysteresis loops below 8 K originating from the Dy3+ ion. Moreover, DyY2N@C80 exhibits TADF originating from the Y3+-coordinated carbon cage, whose luminescence peak positions and peak intensities can be obviously influenced by Dy3+. Furthermore, a supramolecular complex of DyY2N@C80 and [12]Cycloparaphenylene ([12]CPP) was then prepared to construct a single-molecule magnet with multiwavelength luminescence. The effects of host-guest interaction on photoluminescence properties of DyY2N@C80 were disclosed. Theoretical calculations were also employed to illustrate the structures of DyY2N@C80 and DyY2N@C80⊂[12]CPP.
源语言 | 英语 |
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页(从-至) | 19080-19088 |
页数 | 9 |
期刊 | ACS Nano |
卷 | 15 |
期 | 12 |
DOI | |
出版状态 | 已出版 - 28 12月 2021 |
已对外发布 | 是 |