Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

Jing Jiang; Yong Zhang; Hu Wei Liu; Ai Qin Luo; Yu Lin Deng; Jun Ling Gu

Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

Jing Jiang^*
, Yong Zhang
, Hu Wei Liu
, Ai Qin Luo
, Yu Lin Deng
, Jun Ling Gu

^*此作品的通讯作者

Beijing Institute of Technology
China Academy of Engineering Physics
Peking University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 10⁷ plates/m and high resolution. The method was demonstrated to be efficient by comparing with C₁₈-packed column CEC method and high performance liquid chromatography (HPLC) method.

源语言	英语
页（从-至）	372-376
页数	5
期刊	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
卷	25
期	4
出版状态	已出版 - 4月 2005

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title = "Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives",

abstract = "The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.",

keywords = "DB-β-CD, Open-tubular capillary electrochromatography column, Sol-gel",

author = "Jing Jiang and Yong Zhang and Liu, \{Hu Wei\} and Luo, \{Ai Qin\} and Deng, \{Yu Lin\} and Gu, \{Jun Ling\}",

year = "2005",

month = apr,

language = "English",

volume = "25",

pages = "372--376",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "4",

}

TY - JOUR

T1 - Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

AU - Jiang, Jing

AU - Zhang, Yong

AU - Liu, Hu Wei

AU - Luo, Ai Qin

AU - Deng, Yu Lin

AU - Gu, Jun Ling

PY - 2005/4

Y1 - 2005/4

N2 - The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.

AB - The two kinds of by-products produced in TATB synthesis, extracted respectively by toluene and acetone, were separated by open-tube capillary electrochromatography (CEC) on a column coated with sol-gel DB-β-CD as stationary phase. The separation conditions were optimized including the value of pH, the concentration of buffer and the content of organic additives, obtaining the column efficiency of 107 plates/m and high resolution. The method was demonstrated to be efficient by comparing with C18-packed column CEC method and high performance liquid chromatography (HPLC) method.

KW - DB-β-CD

KW - Open-tubular capillary electrochromatography column

KW - Sol-gel

UR - https://www.scopus.com/pages/publications/20444412660

M3 - Article

AN - SCOPUS:20444412660

SN - 1001-0645

VL - 25

SP - 372

EP - 376

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - 4

ER -

Separation of the by-products of the TATB explosives by sol-gel open-tube CEC column of cyclodextrin derivatives

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