Selective oxidation of ethylbenzene with H2O2 over As-V-O cluster

Jianfeng Yu; Jianing Xu; Guoyu Yang; Tonghao Wu; Jiqing Xu; Chiachung Sun

Selective oxidation of ethylbenzene with H₂O₂ over As-V-O cluster

Jianfeng Yu^*
, Jianing Xu
, Guoyu Yang
, Tonghao Wu
, Jiqing Xu
, Chiachung Sun

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

The clusters [N(CH₃)₄]₄ [As₈V₁₄O₄₂(8H₂O)] and its similar materials, such as K₆V₁₀O₂₈·9H₂O, NaKV₂O₆, (H₂En)_0.5V₂O₅, (H₂En)₃(VO)₉(PO₄)₈ and Na₃VO(HPO₄)(PO₄)·H₂O, were synthesized by hydrothermal method. The structure of [N(CH₃)₄]₄[As₈V₁₄O ₄₂(8H₂O)] was characterized by means of XRD and IR. It was indicated that the clusters had excellent catalytic activity for the selective oxidation of C₆H₅C₂H₅ with H₂O₂. Comparing with the compounds without vanadium, the active component for the reaction was discussed.

源语言	英语
页（从-至）	600
页数	1
期刊	Chinese Journal of Catalysis
卷	19
期	6
出版状态	已出版 - 1998
已对外发布	是

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引用此

@article{a340763aabae4b65a8126f8fd2a62d8f,

title = "Selective oxidation of ethylbenzene with H2O2 over As-V-O cluster",

abstract = "The clusters [N(CH3)4]4 [As8V14O42(8H2O)] and its similar materials, such as K6V10O28·9H2O, NaKV2O6, (H2En)0.5V2O5, (H2En)3(VO)9(PO4)8 and Na3VO(HPO4)(PO4)·H2O, were synthesized by hydrothermal method. The structure of [N(CH3)4]4[As8V14O 42(8H2O)] was characterized by means of XRD and IR. It was indicated that the clusters had excellent catalytic activity for the selective oxidation of C6H5C2H5 with H2O2. Comparing with the compounds without vanadium, the active component for the reaction was discussed.",

keywords = "Acetophenone, Arsenic-vanadium-oxygen cluster, Ethylbenzene, Heteropoly acid compound, Hydrogen peroxide, Selective oxidation",

author = "Jianfeng Yu and Jianing Xu and Guoyu Yang and Tonghao Wu and Jiqing Xu and Chiachung Sun",

year = "1998",

language = "English",

volume = "19",

pages = "600",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press",

number = "6",

}

TY - JOUR

T1 - Selective oxidation of ethylbenzene with H2O2 over As-V-O cluster

AU - Yu, Jianfeng

AU - Xu, Jianing

AU - Yang, Guoyu

AU - Wu, Tonghao

AU - Xu, Jiqing

AU - Sun, Chiachung

PY - 1998

Y1 - 1998

N2 - The clusters [N(CH3)4]4 [As8V14O42(8H2O)] and its similar materials, such as K6V10O28·9H2O, NaKV2O6, (H2En)0.5V2O5, (H2En)3(VO)9(PO4)8 and Na3VO(HPO4)(PO4)·H2O, were synthesized by hydrothermal method. The structure of [N(CH3)4]4[As8V14O 42(8H2O)] was characterized by means of XRD and IR. It was indicated that the clusters had excellent catalytic activity for the selective oxidation of C6H5C2H5 with H2O2. Comparing with the compounds without vanadium, the active component for the reaction was discussed.

AB - The clusters [N(CH3)4]4 [As8V14O42(8H2O)] and its similar materials, such as K6V10O28·9H2O, NaKV2O6, (H2En)0.5V2O5, (H2En)3(VO)9(PO4)8 and Na3VO(HPO4)(PO4)·H2O, were synthesized by hydrothermal method. The structure of [N(CH3)4]4[As8V14O 42(8H2O)] was characterized by means of XRD and IR. It was indicated that the clusters had excellent catalytic activity for the selective oxidation of C6H5C2H5 with H2O2. Comparing with the compounds without vanadium, the active component for the reaction was discussed.

KW - Acetophenone

KW - Arsenic-vanadium-oxygen cluster

KW - Ethylbenzene

KW - Heteropoly acid compound

KW - Hydrogen peroxide

KW - Selective oxidation

UR - https://www.scopus.com/pages/publications/11744301559

M3 - Article

AN - SCOPUS:11744301559

SN - 1872-2067

VL - 19

SP - 600

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 6

ER -

Selective oxidation of ethylbenzene with H2O2 over As-V-O cluster

摘要

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Selective oxidation of ethylbenzene with H₂O₂ over As-V-O cluster