Rhodium-catalyzed hydroselenation of unsymmetric 1,3-dienes with 3,4-Markovnikov regioselectivity

Anee Taj; Chen Cui; Zhenwei Shi; Xuebin Huang; Xiao Hui Yang

doi:10.1039/d5qo00926j

Rhodium-catalyzed hydroselenation of unsymmetric 1,3-dienes with 3,4-Markovnikov regioselectivity

Anee Taj
, Chen Cui
, Zhenwei Shi
, Xuebin Huang^*
, Xiao Hui Yang^*

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

1 引用（Scopus）

摘要

Catalytic hydroselenation of alkenes represents one of the most direct and efficient methods for organoselenide synthesis. In this study, we report a highly regioselective Rh-catalyzed hydroselenation of unsymmetric 1,3-dienes, including internal unsymmetric dienes. This atom-economical method operates under mild conditions and selectively affords 3,4-Markovnikov products with excellent regiocontrol. The developed protocol was effective in reactions involving both internal and terminal dienes.

源语言	英语
页（从-至）	6401-6406
页数	6
期刊	Organic Chemistry Frontiers
卷	12
期	23
DOI	https://doi.org/10.1039/d5qo00926j
出版状态	已出版 - 7 12月 2025

访问文件

10.1039/d5qo00926j

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{2c7d518c337e40258ad950b50b0407d3,

title = "Rhodium-catalyzed hydroselenation of unsymmetric 1,3-dienes with 3,4-Markovnikov regioselectivity",

abstract = "Catalytic hydroselenation of alkenes represents one of the most direct and efficient methods for organoselenide synthesis. In this study, we report a highly regioselective Rh-catalyzed hydroselenation of unsymmetric 1,3-dienes, including internal unsymmetric dienes. This atom-economical method operates under mild conditions and selectively affords 3,4-Markovnikov products with excellent regiocontrol. The developed protocol was effective in reactions involving both internal and terminal dienes.",

author = "Anee Taj and Chen Cui and Zhenwei Shi and Xuebin Huang and Yang, \{Xiao Hui\}",

note = "Publisher Copyright: This journal is {\textcopyright} the Partner Organisations, 2025",

year = "2025",

month = dec,

day = "7",

doi = "10.1039/d5qo00926j",

language = "English",

volume = "12",

pages = "6401--6406",

journal = "Organic Chemistry Frontiers",

issn = "2052-4110",

publisher = "Royal Society of Chemistry",

number = "23",

}

TY - JOUR

T1 - Rhodium-catalyzed hydroselenation of unsymmetric 1,3-dienes with 3,4-Markovnikov regioselectivity

AU - Taj, Anee

AU - Cui, Chen

AU - Shi, Zhenwei

AU - Huang, Xuebin

AU - Yang, Xiao Hui

PY - 2025/12/7

Y1 - 2025/12/7

N2 - Catalytic hydroselenation of alkenes represents one of the most direct and efficient methods for organoselenide synthesis. In this study, we report a highly regioselective Rh-catalyzed hydroselenation of unsymmetric 1,3-dienes, including internal unsymmetric dienes. This atom-economical method operates under mild conditions and selectively affords 3,4-Markovnikov products with excellent regiocontrol. The developed protocol was effective in reactions involving both internal and terminal dienes.

AB - Catalytic hydroselenation of alkenes represents one of the most direct and efficient methods for organoselenide synthesis. In this study, we report a highly regioselective Rh-catalyzed hydroselenation of unsymmetric 1,3-dienes, including internal unsymmetric dienes. This atom-economical method operates under mild conditions and selectively affords 3,4-Markovnikov products with excellent regiocontrol. The developed protocol was effective in reactions involving both internal and terminal dienes.

UR - https://www.scopus.com/pages/publications/105018197701

U2 - 10.1039/d5qo00926j

DO - 10.1039/d5qo00926j

M3 - Article

AN - SCOPUS:105018197701

SN - 2052-4110

VL - 12

SP - 6401

EP - 6406

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 23

ER -

Rhodium-catalyzed hydroselenation of unsymmetric 1,3-dienes with 3,4-Markovnikov regioselectivity

摘要

访问文件

其它文件与链接

指纹

引用此