Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

Jiajia Li; Xiao Peng Sun; Shiqi Bi; Minglu Xu; Siyu Jia; Zheng Tang; Pengtao Ma; Jingping Wang; Jun Tao; Jingyang Niu

doi:10.1021/acs.inorgchem.2c03032

Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

Jiajia Li
, Xiao Peng Sun^*
, Shiqi Bi
, Minglu Xu
, Siyu Jia
, Zheng Tang
, Pengtao Ma
, Jingping Wang
, Jun Tao
, Jingyang Niu^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

12 引用（Scopus）

摘要

Polyoxometalate (POM) anions were successfully integrated into Fe(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe(II) ion in the identical cation [Fe(bpp)₂]²⁺were achieved by leveraging [Mo₆O₁₉]^2-, [Mo₈O₂₆]^4-, and [Na(Mo₈O₂₆)]^3-, respectively.

源语言	英语
页（从-至）	17932-17936
页数	5
期刊	Inorganic Chemistry
卷	61
期	45
DOI	https://doi.org/10.1021/acs.inorgchem.2c03032
出版状态	已出版 - 14 11月 2022

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10.1021/acs.inorgchem.2c03032

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title = "Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System",

abstract = "Polyoxometalate (POM) anions were successfully integrated into Fe(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe(II) ion in the identical cation [Fe(bpp)2]2+were achieved by leveraging [Mo6O19]2-, [Mo8O26]4-, and [Na(Mo8O26)]3-, respectively.",

author = "Jiajia Li and Sun, \{Xiao Peng\} and Shiqi Bi and Minglu Xu and Siyu Jia and Zheng Tang and Pengtao Ma and Jingping Wang and Jun Tao and Jingyang Niu",

year = "2022",

month = nov,

day = "14",

doi = "10.1021/acs.inorgchem.2c03032",

language = "English",

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T1 - Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

AU - Li, Jiajia

AU - Sun, Xiao Peng

AU - Bi, Shiqi

AU - Xu, Minglu

AU - Jia, Siyu

AU - Tang, Zheng

AU - Ma, Pengtao

AU - Wang, Jingping

AU - Tao, Jun

AU - Niu, Jingyang

PY - 2022/11/14

Y1 - 2022/11/14

N2 - Polyoxometalate (POM) anions were successfully integrated into Fe(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe(II) ion in the identical cation [Fe(bpp)2]2+were achieved by leveraging [Mo6O19]2-, [Mo8O26]4-, and [Na(Mo8O26)]3-, respectively.

AB - Polyoxometalate (POM) anions were successfully integrated into Fe(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe(II) ion in the identical cation [Fe(bpp)2]2+were achieved by leveraging [Mo6O19]2-, [Mo8O26]4-, and [Na(Mo8O26)]3-, respectively.

UR - https://www.scopus.com/pages/publications/85141612989

U2 - 10.1021/acs.inorgchem.2c03032

DO - 10.1021/acs.inorgchem.2c03032

M3 - Article

C2 - 36321822

AN - SCOPUS:85141612989

SN - 0020-1669

VL - 61

SP - 17932

EP - 17936

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 45

ER -

Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

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