Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu; Mu Hua Huang

doi:10.1021/ol0609210

Radicamines A and B: Synthesis and revision of the absolute configuration

Chu Yi Yu^*
, Mu Hua Huang

^*此作品的通讯作者

CAS - Institute of Chemistry
University of Chinese Academy of Sciences

科研成果: 期刊稿件 › 文章 › 同行评审

86 引用（Scopus）

摘要

Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both ¹H and ¹³C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

源语言	英语
页（从-至）	3021-3024
页数	4
期刊	Organic Letters
卷	8
期	14
DOI	https://doi.org/10.1021/ol0609210
出版状态	已出版 - 6 7月 2006
已对外发布	是

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title = "Radicamines A and B: Synthesis and revision of the absolute configuration",

abstract = "Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.",

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AB - Starting from D-xylose, enantioselective syntheses of 1 and 2, the proposed structures for radicamines A and B, were accomplished. Both 1H and 13C NMR spectra of 1 and 2 were identical with those of the natural products, but the optical rotation measurements identified that 1 and 2 were actually the enantiomers of the natural radicamines A and B, respectively.

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Radicamines A and B: Synthesis and revision of the absolute configuration

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