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Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology

  • Yue Ling Bai
  • , Jun Tao*
  • , Rong Bin Huang
  • , Lan Sun Zheng
  • , Shao Liang Zheng
  • , Kazuyoshi Oshida
  • , Yasuaki Einaga
  • *此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

A three-dimensional mixed-valence iron complex with NiAs-type topology, [(FeIII3O)FeII(TA)6(H 2O)3]•(ClO4)2(NO 3)(EtOH)(H2O)2 (1, HTA = tetrazole-1H-acetic acid), shows spin-crossover behavior that was characterized via variable-temperature crystal structures, Mössbauer spectra and magnetic susceptibilities, the pressure effects on the transition behavior were also studied.

源语言英语
页(从-至)1753-1755
页数3
期刊Chemical Communications
15
DOI
出版状态已出版 - 2008
已对外发布

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