Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors

Yanpeng Xing; Guorong Sheng; Jing Wang; Ping Lu; Yanguang Wang

doi:10.1021/ol5002347

Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors

Yanpeng Xing
, Guorong Sheng
, Jing Wang
, Ping Lu^*
, Yanguang Wang

^*此作品的通讯作者

Zhejiang University

科研成果: 期刊稿件 › 文章 › 同行评审

151 引用（Scopus）

摘要

3-Sulfonyl[1,2,3]triazolo[4,5-b]indoles were efficiently prepared via a tandem catalysis process involving intramolecular ligand stabilized CuAAC and Cu-catalyzed C-N coupling. The obtained 3-sulfonyl[1,2,3]triazolo[4,5-b]indoles could be utilized as α-imino rhodium carbene precursors for the construction of a range of valuable indole molecules including pyrrolo[2,3-b]indoles, spirocyclopropyl iminoindoles, 2,3-dihydropyrrolo[2,3-b] indoles, 3,3′-biindoles, and 2,3′-biindoles.

源语言	英语
页（从-至）	1244-1247
页数	4
期刊	Organic Letters
卷	16
期	4
DOI	https://doi.org/10.1021/ol5002347
出版状态	已出版 - 21 2月 2014
已对外发布	是

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title = "Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors",

abstract = "3-Sulfonyl[1,2,3]triazolo[4,5-b]indoles were efficiently prepared via a tandem catalysis process involving intramolecular ligand stabilized CuAAC and Cu-catalyzed C-N coupling. The obtained 3-sulfonyl[1,2,3]triazolo[4,5-b]indoles could be utilized as α-imino rhodium carbene precursors for the construction of a range of valuable indole molecules including pyrrolo[2,3-b]indoles, spirocyclopropyl iminoindoles, 2,3-dihydropyrrolo[2,3-b] indoles, 3,3′-biindoles, and 2,3′-biindoles.",

author = "Yanpeng Xing and Guorong Sheng and Jing Wang and Ping Lu and Yanguang Wang",

year = "2014",

month = feb,

day = "21",

doi = "10.1021/ol5002347",

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TY - JOUR

T1 - Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors

AU - Xing, Yanpeng

AU - Sheng, Guorong

AU - Wang, Jing

AU - Lu, Ping

AU - Wang, Yanguang

PY - 2014/2/21

Y1 - 2014/2/21

N2 - 3-Sulfonyl[1,2,3]triazolo[4,5-b]indoles were efficiently prepared via a tandem catalysis process involving intramolecular ligand stabilized CuAAC and Cu-catalyzed C-N coupling. The obtained 3-sulfonyl[1,2,3]triazolo[4,5-b]indoles could be utilized as α-imino rhodium carbene precursors for the construction of a range of valuable indole molecules including pyrrolo[2,3-b]indoles, spirocyclopropyl iminoindoles, 2,3-dihydropyrrolo[2,3-b] indoles, 3,3′-biindoles, and 2,3′-biindoles.

AB - 3-Sulfonyl[1,2,3]triazolo[4,5-b]indoles were efficiently prepared via a tandem catalysis process involving intramolecular ligand stabilized CuAAC and Cu-catalyzed C-N coupling. The obtained 3-sulfonyl[1,2,3]triazolo[4,5-b]indoles could be utilized as α-imino rhodium carbene precursors for the construction of a range of valuable indole molecules including pyrrolo[2,3-b]indoles, spirocyclopropyl iminoindoles, 2,3-dihydropyrrolo[2,3-b] indoles, 3,3′-biindoles, and 2,3′-biindoles.

UR - https://www.scopus.com/pages/publications/84894527266

U2 - 10.1021/ol5002347

DO - 10.1021/ol5002347

M3 - Article

C2 - 24517549

AN - SCOPUS:84894527266

SN - 1523-7060

VL - 16

SP - 1244

EP - 1247

JO - Organic Letters

JF - Organic Letters

IS - 4

ER -

Preparation of triazoloindoles via tandem copper catalysis and their utility as α-imino rhodium carbene precursors

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