TY - JOUR
T1 - Preparation of the chitosan grafted poly (quaternary ammonium)/Fe3O4 nanoparticles and its adsorption performance for food yellow 3
AU - Yu, Chen
AU - Geng, Jianqiang
AU - Zhuang, Yunxia
AU - Zhao, Jian
AU - Chu, Liqiu
AU - Luo, Xiaoxuan
AU - Zhao, Ying
AU - Guo, Yanwen
N1 - Publisher Copyright:
© 2016 Elsevier Ltd
PY - 2016/11/5
Y1 - 2016/11/5
N2 - Chitosan and its derivatives can be used to modify magnetic materials to promote the adsorption properties of the magnetic materials and avoid the weakness of chitosan and its derivatives. In the present study, chitosan grafted poly(trimethyl allyl ammonium chloride) (CTS-g-PTMAAC) was prepared by graft copolymerization; then it was coated on the surfaces of the sodium citrate coated Fe3O4 nanoparticles (SC-Fe3O4) to prepare a novel composite CTS-g-PTMAAC/SC-Fe3O4 magnetic nanoparticles, with which possesses abundant surface positive charges. The structure and properties of the CTS-g-PTMAAC/SC-Fe3O4 composite magnetic nanoparticles were characterized by FTIR, TEM, VSM, and zeta potential. The dye adsorption characteristics of the CTS-g-PTMAAC/SC-Fe3O4 nanoparticles were determined using the food yellow 3 aqueous solutions as a model food effluent. Effect of pH of the dye solution on the adsorption of food yellow 3 was determined and compared with N-2-hydroxylpropyl trimethyl ammonium chloride chitosan coated sodium citrate-Fe3O4 (CTS-g-HTCC/SC-Fe3O4) composite magnetic nanoparticles. The adsorption kinetics, adsorption isotherms, adsorption thermodynamics, and desorption and reusability of the magnetic nanoparticles were investigated.
AB - Chitosan and its derivatives can be used to modify magnetic materials to promote the adsorption properties of the magnetic materials and avoid the weakness of chitosan and its derivatives. In the present study, chitosan grafted poly(trimethyl allyl ammonium chloride) (CTS-g-PTMAAC) was prepared by graft copolymerization; then it was coated on the surfaces of the sodium citrate coated Fe3O4 nanoparticles (SC-Fe3O4) to prepare a novel composite CTS-g-PTMAAC/SC-Fe3O4 magnetic nanoparticles, with which possesses abundant surface positive charges. The structure and properties of the CTS-g-PTMAAC/SC-Fe3O4 composite magnetic nanoparticles were characterized by FTIR, TEM, VSM, and zeta potential. The dye adsorption characteristics of the CTS-g-PTMAAC/SC-Fe3O4 nanoparticles were determined using the food yellow 3 aqueous solutions as a model food effluent. Effect of pH of the dye solution on the adsorption of food yellow 3 was determined and compared with N-2-hydroxylpropyl trimethyl ammonium chloride chitosan coated sodium citrate-Fe3O4 (CTS-g-HTCC/SC-Fe3O4) composite magnetic nanoparticles. The adsorption kinetics, adsorption isotherms, adsorption thermodynamics, and desorption and reusability of the magnetic nanoparticles were investigated.
KW - Adsorption
KW - Chitosan
KW - Composite magnetic nanoparticles
KW - Food dye
KW - Poly (quaternary ammonium)
UR - https://www.scopus.com/pages/publications/84978218332
U2 - 10.1016/j.carbpol.2016.06.114
DO - 10.1016/j.carbpol.2016.06.114
M3 - Article
C2 - 27516279
AN - SCOPUS:84978218332
SN - 0144-8617
VL - 152
SP - 327
EP - 336
JO - Carbohydrate Polymers
JF - Carbohydrate Polymers
ER -