Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

Heng Dao Quan; Hui e. Yang; Zhong Li; Jian Zhang Ren; Hui Li Li

doi:10.1016/S0022-1139(01)00453-5

Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

Heng Dao Quan
, Hui e. Yang
, Zhong Li
, Jian Zhang Ren
, Hui Li Li

Xi'an Modern Chemistry Research Institute
National Institute of Advanced Industrial Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

1,1,1,2-Tetrafluoroethane was prepared in 97% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF₃ and CoF₂) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.

源语言	英语
页（从-至）	193-199
页数	7
期刊	Journal of Fluorine Chemistry
卷	111
期	2
DOI	https://doi.org/10.1016/S0022-1139(01)00453-5
出版状态	已出版 - 2001
已对外发布	是

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title = "Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride",

abstract = "1,1,1,2-Tetrafluoroethane was prepared in 97\% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF3 and CoF2) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.",

keywords = "1,1,1,2-Tetrafluoroethane, 1,1,1-Trifluoro-2-chloroethane, Metal fluoride, Porous aluminum fluoride",

author = "Quan, \{Heng Dao\} and Yang, \{Hui e.\} and Zhong Li and Ren, \{Jian Zhang\} and Li, \{Hui Li\}",

year = "2001",

doi = "10.1016/S0022-1139(01)00453-5",

language = "English",

volume = "111",

pages = "193--199",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

number = "2",

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TY - JOUR

T1 - Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

AU - Quan, Heng Dao

AU - Yang, Hui e.

AU - Li, Zhong

AU - Ren, Jian Zhang

AU - Li, Hui Li

PY - 2001

Y1 - 2001

N2 - 1,1,1,2-Tetrafluoroethane was prepared in 97% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF3 and CoF2) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.

AB - 1,1,1,2-Tetrafluoroethane was prepared in 97% selectivity by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride (AHF) over a metal fluoride catalyst (CrF3 and CoF2) supported on porous aluminum fluoride (PAF). The relationship between the crystalline phase transition of porous aluminum fluoride and temperature from 100 to 640°C was investigated by X-ray diffraction.

KW - 1,1,1,2-Tetrafluoroethane

KW - 1,1,1-Trifluoro-2-chloroethane

KW - Metal fluoride

KW - Porous aluminum fluoride

UR - https://www.scopus.com/pages/publications/0034814833

U2 - 10.1016/S0022-1139(01)00453-5

DO - 10.1016/S0022-1139(01)00453-5

M3 - Article

AN - SCOPUS:0034814833

SN - 0022-1139

VL - 111

SP - 193

EP - 199

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 2

ER -

Preparation of 1,1,1,2-tetrafluoroethane by the vapor-phase catalytic reaction of 1,1,1-trifluoro-2-chloroethane with anhydrous hydrogen fluoride

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