Polyoxometalate-mediated syntheses of three structurally new silver clusters

Jing Zhang; Yuanyuan Dong; Lan Deng; Manzhou Chi; Yeqin Feng; Mengyun Zhao; Hongjin Lv; Guo Yu Yang

doi:10.1039/d4nr02016b

Polyoxometalate-mediated syntheses of three structurally new silver clusters

Jing Zhang
, Yuanyuan Dong
, Lan Deng
, Manzhou Chi
, Yeqin Feng
, Mengyun Zhao
, Hongjin Lv^*
, Guo Yu Yang

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

18 引用（Scopus）

摘要

Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW₉O₃₄)@Ag₂₄(ⁱPrS)₁₁(DPPP)₆Cl]₂(SiW₁₂O₄₀) (Ag₂₄), heterometallic [(SiW₉O₃₄)@Ag₂₂Cu(ⁱPrS)₁₁(DPPP)₆Cl](SbF₆)₂ (Ag₂₂Cu) and {Ag₁₆(ⁱPrS)₆(DPPP)₈(CH₃COO)₄[Co₄(OH)₃(H₂O)SiW₉O₃₃]₂}·(CH₃CN)₄ (Ag₁₆Co₈) (ⁱPrS⁻ = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF₆⁻ = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.

源语言	英语
页（从-至）	11518-11523
页数	6
期刊	Nanoscale
卷	16
期	24
DOI	https://doi.org/10.1039/d4nr02016b
出版状态	已出版 - 27 5月 2024
已对外发布	是

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@article{42c7d347f1dc4b1d95d1844bbfb49796,

title = "Polyoxometalate-mediated syntheses of three structurally new silver clusters",

abstract = "Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW9O34)@Ag24(iPrS)11(DPPP)6Cl]2(SiW12O40) (Ag24), heterometallic [(SiW9O34)@Ag22Cu(iPrS)11(DPPP)6Cl](SbF6)2 (Ag22Cu) and \{Ag16(iPrS)6(DPPP)8(CH3COO)4[Co4(OH)3(H2O)SiW9O33]2\}·(CH3CN)4 (Ag16Co8) (iPrS− = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF6− = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.",

author = "Jing Zhang and Yuanyuan Dong and Lan Deng and Manzhou Chi and Yeqin Feng and Mengyun Zhao and Hongjin Lv and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry.",

year = "2024",

month = may,

day = "27",

doi = "10.1039/d4nr02016b",

language = "English",

volume = "16",

pages = "11518--11523",

journal = "Nanoscale",

issn = "2040-3364",

publisher = "Royal Society of Chemistry",

number = "24",

}

TY - JOUR

T1 - Polyoxometalate-mediated syntheses of three structurally new silver clusters

AU - Zhang, Jing

AU - Dong, Yuanyuan

AU - Deng, Lan

AU - Chi, Manzhou

AU - Feng, Yeqin

AU - Zhao, Mengyun

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2024/5/27

Y1 - 2024/5/27

N2 - Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW9O34)@Ag24(iPrS)11(DPPP)6Cl]2(SiW12O40) (Ag24), heterometallic [(SiW9O34)@Ag22Cu(iPrS)11(DPPP)6Cl](SbF6)2 (Ag22Cu) and {Ag16(iPrS)6(DPPP)8(CH3COO)4[Co4(OH)3(H2O)SiW9O33]2}·(CH3CN)4 (Ag16Co8) (iPrS− = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF6− = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.

AB - Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW9O34)@Ag24(iPrS)11(DPPP)6Cl]2(SiW12O40) (Ag24), heterometallic [(SiW9O34)@Ag22Cu(iPrS)11(DPPP)6Cl](SbF6)2 (Ag22Cu) and {Ag16(iPrS)6(DPPP)8(CH3COO)4[Co4(OH)3(H2O)SiW9O33]2}·(CH3CN)4 (Ag16Co8) (iPrS− = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF6− = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.

UR - https://www.scopus.com/pages/publications/85195039901

U2 - 10.1039/d4nr02016b

DO - 10.1039/d4nr02016b

M3 - Article

AN - SCOPUS:85195039901

SN - 2040-3364

VL - 16

SP - 11518

EP - 11523

JO - Nanoscale

JF - Nanoscale

IS - 24

ER -

Polyoxometalate-mediated syntheses of three structurally new silver clusters

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