Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

Xiao Dong Yang; Rui Zhu; Li Sun; Rui Yun Guo; Jie Zhang

doi:10.1021/acs.inorgchem.7b03108

Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

Xiao Dong Yang
, Rui Zhu
, Li Sun
, Rui Yun Guo
, Jie Zhang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

21 引用（Scopus）

摘要

Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

源语言	英语
页（从-至）	2724-2729
页数	6
期刊	Inorganic Chemistry
卷	57
期	5
DOI	https://doi.org/10.1021/acs.inorgchem.7b03108
出版状态	已出版 - 5 3月 2018

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10.1021/acs.inorgchem.7b03108

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title = "Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer",

abstract = "Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine {"}heart{"} is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine {"}heart{"} promotes the occurrence of this mechanical movement.",

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AU - Yang, Xiao Dong

AU - Zhu, Rui

AU - Sun, Li

AU - Guo, Rui Yun

AU - Zhang, Jie

PY - 2018/3/5

Y1 - 2018/3/5

N2 - Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

AB - Photomechanical movement with a morphological deformation has been achieved in the crystalline state of a bipyridinium-based coordination polymer. The engine "heart" is the electron-deficient bipyridinium core sandwiched by electron-rich phenylcarboxylate components. The decorrelation of the CT state triggered by PET reaction in the engine "heart" promotes the occurrence of this mechanical movement.

UR - https://www.scopus.com/pages/publications/85043290306

U2 - 10.1021/acs.inorgchem.7b03108

DO - 10.1021/acs.inorgchem.7b03108

M3 - Article

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Phototriggered Mechanical Movement in A Bipyridinium-based Coordination Polymer Powered by Electron Transfer

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