Pentaethylenehexaminemanganese(II) pentaborate

Hong Xia Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1107/S0108270104007942

Pentaethylenehexaminemanganese(II) pentaborate

Hong Xia Zhang
, Shou Tian Zheng
, Guo Yu Yang^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

39 引用（Scopus）

摘要

The title compound, (pentaethylenehexamine-κ⁶N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C₁₀H₂₈N ₆)][B₅O₆(OH)₄]₂, was synthesized under mild solvothermal conditions. The B₅O ₆(OH)₄^- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C₁₀H₂₈N ₆)]^2- cations are located. The Mn^II complex cation has a twofold axis and the coordination geometry of the MnN₆ group is that of a distorted trigonal prism.

源语言	英语
页（从-至）	m241-m243
期刊	Acta Crystallographica Section C: Crystal Structure Communications
卷	60
期	6
DOI	https://doi.org/10.1107/S0108270104007942
出版状态	已出版 - 6月 2004
已对外发布	是

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title = "Pentaethylenehexaminemanganese(II) pentaborate",

abstract = "The title compound, (pentaethylenehexamine-κ6N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C10H28N 6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O 6(OH)4- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N 6)]2- cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.",

author = "Zhang, \{Hong Xia\} and Zheng, \{Shou Tian\} and Yang, \{Guo Yu\}",

year = "2004",

month = jun,

doi = "10.1107/S0108270104007942",

language = "English",

volume = "60",

pages = "m241--m243",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "6",

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TY - JOUR

T1 - Pentaethylenehexaminemanganese(II) pentaborate

AU - Zhang, Hong Xia

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/6

Y1 - 2004/6

N2 - The title compound, (pentaethylenehexamine-κ6N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C10H28N 6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O 6(OH)4- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N 6)]2- cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.

AB - The title compound, (pentaethylenehexamine-κ6N) manganese(II) 4,4′,6,6′-tetrahydroxy-2,2′- spirobi(cyclotriboroxane)(1-), [Mn(C10H28N 6)][B5O6(OH)4]2, was synthesized under mild solvothermal conditions. The B5O 6(OH)4- units are connected to one another via hydrogen bonds, forming a three-dimensional framework with large channels along the a and c axes, in which the templating [Mn(C10H28N 6)]2- cations are located. The MnII complex cation has a twofold axis and the coordination geometry of the MnN6 group is that of a distorted trigonal prism.

UR - https://www.scopus.com/pages/publications/3142641344

U2 - 10.1107/S0108270104007942

DO - 10.1107/S0108270104007942

M3 - Article

AN - SCOPUS:3142641344

SN - 0108-2701

VL - 60

SP - m241-m243

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

Pentaethylenehexaminemanganese(II) pentaborate

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