TY - JOUR
T1 - [Pb(en)0.5][B5O8(OH)]
T2 - A New Bilayered Organic–Inorganic Hybrid Lead Borate Built by B5O8(OH) Cluster Units
AU - Ma, Lan
AU - He, Huan
AU - Yang, Bai Feng
AU - Zhang, Qiang
AU - Yang, Guo Yu
N1 - Publisher Copyright:
© 2015, Springer Science+Business Media New York.
PY - 2015/9/24
Y1 - 2015/9/24
N2 - A new layered organic–inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) Å, b = 6.7157(6) Å, c = 10.6911(9) Å, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) Å3, Z = 2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure.
AB - A new layered organic–inorganic hybrid lead borate [Pb(en)0.5][B5O8(OH)] (1, en = ethylenediamine), has been hydro(solvo)thermally synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, FT-IR spectroscopy and thermogravimetric analysis, respectively. Compound 1 crystallizes in triclinic system space group P-1 (No. 2), a = 6.6537(6) Å, b = 6.7157(6) Å, c = 10.6911(9) Å, α = 99.015(7)°, β = 93.657(7)°, γ = 118.915(9)°, V = 407.59(6) Å3, Z = 2. The structure consists of two infinite borate layers constructed from [B5O8(OH)]2− cluster building units, then two such layers are further connected by the linear [Pb2(en)]4+ complex linkers to form the novel bilayer structure.
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Lead
KW - Lead borate
KW - Oxo boron cluster
UR - https://www.scopus.com/pages/publications/84939772203
U2 - 10.1007/s10876-015-0840-7
DO - 10.1007/s10876-015-0840-7
M3 - Article
AN - SCOPUS:84939772203
SN - 1040-7278
VL - 26
SP - 1495
EP - 1502
JO - Journal of Cluster Science
JF - Journal of Cluster Science
IS - 5
ER -