Organocatalytic Asymmetric Michael/Cyclization Cascade Reaction of 3-Isothiocyanato Oxindoles with Maleimides for the Efficient Construction of Pyrrolidonyl Spirooxindoles

Lei Liu, Bo Liang Zhao, Da Ming Du*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

32 引用 (Scopus)

摘要

The development of a Michael/cyclization cascade reaction between 3-isothiocyanato-oxindoles and maleimide catalyzed by chrial squaramides is reported. This protocol provides a series of pyrrolidonyl spirooxindoles bearing three contiguous stereocenters in excellent yields (up to 99 %) with high diastereo- and enantioselectivities (up to >99:1 dr, 91 % ee).

源语言英语
页(从-至)4711-4718
页数8
期刊European Journal of Organic Chemistry
2016
27
DOI
出版状态已出版 - 9月 2016

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