Novel Dimethylmethylene-Bridged Triphenylamine-PDI Acceptor for Bulk-Heterojunction Organic Solar Cells

Yu Xiong; Bo Wu; Xiaoyan Zheng; Zheng Zhao; Ping Deng; Ming Lin; Benzhong Tang; Beng S. Ong

doi:10.1002/advs.201700110

Novel Dimethylmethylene-Bridged Triphenylamine-PDI Acceptor for Bulk-Heterojunction Organic Solar Cells

Yu Xiong
, Bo Wu
, Xiaoyan Zheng
, Zheng Zhao
, Ping Deng
, Ming Lin
, Benzhong Tang
, Beng S. Ong^*

^*此作品的通讯作者

Research Centre of Excellence for Organic Electronics
Hong Kong Baptist University
Hong Kong University of Science and Technology
Department of Chemistry
Agency for Science, Technology and Research, Singapore

科研成果: 期刊稿件 › 文章 › 同行评审

31 引用（Scopus）

摘要

A novel, star-shaped electron acceptor, DMTPA-PDI₃, derived from a planar dimethylmethylene-bridged triphenylamine core with three acetylene-linked perylene diimide (PDI) units is developed as a nonfullerene acceptor for organic solar cells (OSCs). DMTPA-PDI₃ manifests significantly reduced intramolecular twisting, enabling sufficient system-wide π-electron delocalization leading to broadened spectral absorption and raised lowest unoccupied molecular orbital level. As a result, higher and more balanced hole and electron transport properties are observed. Active layers for OSCs comprising DMTPA-PDI₃ acceptor and PBT7-Th donor exhibit suppressed intermolecular aggregation, giving rise to uniform nanophase network formation. These OSC devices have afforded respectably high power-conversion efficiency of about 5%.

源语言	英语
期刊论文编号	1700110
期刊	Advanced Science
卷	4
期	10
DOI	https://doi.org/10.1002/advs.201700110
出版状态	已出版 - 10月 2017
已对外发布	是

访问文件

10.1002/advs.201700110

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{1d8cf6b702204f8d8064c655208ef3a9,

title = "Novel Dimethylmethylene-Bridged Triphenylamine-PDI Acceptor for Bulk-Heterojunction Organic Solar Cells",

abstract = "A novel, star-shaped electron acceptor, DMTPA-PDI3, derived from a planar dimethylmethylene-bridged triphenylamine core with three acetylene-linked perylene diimide (PDI) units is developed as a nonfullerene acceptor for organic solar cells (OSCs). DMTPA-PDI3 manifests significantly reduced intramolecular twisting, enabling sufficient system-wide π-electron delocalization leading to broadened spectral absorption and raised lowest unoccupied molecular orbital level. As a result, higher and more balanced hole and electron transport properties are observed. Active layers for OSCs comprising DMTPA-PDI3 acceptor and PBT7-Th donor exhibit suppressed intermolecular aggregation, giving rise to uniform nanophase network formation. These OSC devices have afforded respectably high power-conversion efficiency of about 5\%.",

keywords = "nonfullerene acceptors, organic solar cells, perylene diimide, triphenylamine",

author = "Yu Xiong and Bo Wu and Xiaoyan Zheng and Zheng Zhao and Ping Deng and Ming Lin and Benzhong Tang and Ong, \{Beng S.\}",

note = "Publisher Copyright: {\textcopyright} 2017 The Authors. Published by WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = oct,

doi = "10.1002/advs.201700110",

language = "English",

volume = "4",

journal = "Advanced Science",

issn = "2198-3844",

number = "10",

}

TY - JOUR

T1 - Novel Dimethylmethylene-Bridged Triphenylamine-PDI Acceptor for Bulk-Heterojunction Organic Solar Cells

AU - Xiong, Yu

AU - Wu, Bo

AU - Zheng, Xiaoyan

AU - Zhao, Zheng

AU - Deng, Ping

AU - Lin, Ming

AU - Tang, Benzhong

AU - Ong, Beng S.

PY - 2017/10

Y1 - 2017/10

N2 - A novel, star-shaped electron acceptor, DMTPA-PDI3, derived from a planar dimethylmethylene-bridged triphenylamine core with three acetylene-linked perylene diimide (PDI) units is developed as a nonfullerene acceptor for organic solar cells (OSCs). DMTPA-PDI3 manifests significantly reduced intramolecular twisting, enabling sufficient system-wide π-electron delocalization leading to broadened spectral absorption and raised lowest unoccupied molecular orbital level. As a result, higher and more balanced hole and electron transport properties are observed. Active layers for OSCs comprising DMTPA-PDI3 acceptor and PBT7-Th donor exhibit suppressed intermolecular aggregation, giving rise to uniform nanophase network formation. These OSC devices have afforded respectably high power-conversion efficiency of about 5%.

AB - A novel, star-shaped electron acceptor, DMTPA-PDI3, derived from a planar dimethylmethylene-bridged triphenylamine core with three acetylene-linked perylene diimide (PDI) units is developed as a nonfullerene acceptor for organic solar cells (OSCs). DMTPA-PDI3 manifests significantly reduced intramolecular twisting, enabling sufficient system-wide π-electron delocalization leading to broadened spectral absorption and raised lowest unoccupied molecular orbital level. As a result, higher and more balanced hole and electron transport properties are observed. Active layers for OSCs comprising DMTPA-PDI3 acceptor and PBT7-Th donor exhibit suppressed intermolecular aggregation, giving rise to uniform nanophase network formation. These OSC devices have afforded respectably high power-conversion efficiency of about 5%.

KW - nonfullerene acceptors

KW - organic solar cells

KW - perylene diimide

KW - triphenylamine

UR - https://www.scopus.com/pages/publications/85021253260

U2 - 10.1002/advs.201700110

DO - 10.1002/advs.201700110

M3 - Article

AN - SCOPUS:85021253260

SN - 2198-3844

VL - 4

JO - Advanced Science

JF - Advanced Science

IS - 10

M1 - 1700110

ER -

Novel Dimethylmethylene-Bridged Triphenylamine-PDI Acceptor for Bulk-Heterojunction Organic Solar Cells

摘要

访问文件

其它文件与链接

学术指纹

引用此