TY - JOUR
T1 - Nitrogen-rich energetic monoanionic salts of 3,4-bis(1 H-5-tetrazolyl) furoxan
AU - Huang, Haifeng
AU - Zhou, Zhiming
AU - Liang, Lixuan
AU - Song, Jinhong
AU - Wang, Kai
AU - Cao, Dan
AU - Sun, Wenwen
AU - Bian, Chengming
AU - Xue, Min
PY - 2012/4
Y1 - 2012/4
N2 - 3,4-Bis(1H-5-tetrazolyl)furoxan (H 2BTF, 2) and its monoanionic salts that contain nitrogen-rich cations were readily synthesized and fully characterized by multinuclear NMR ( 1H, 13C) and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Hydrazinium (3) and 4-amino-1,2,4-triazolium (7) salts crystallized in the monoclinic space group P2(1)/n and have calculated densities of 1.820 and 1.764 g cm -3, respectively. The densities of the energetic salts range between 1.63 and 1.79 g cm -3, as measured by a gas pycnometer. Detonation pressures and detonation velocities were calculated to be 23.1-32.5 GPa and 7740-8790 m s -1, respectively.
AB - 3,4-Bis(1H-5-tetrazolyl)furoxan (H 2BTF, 2) and its monoanionic salts that contain nitrogen-rich cations were readily synthesized and fully characterized by multinuclear NMR ( 1H, 13C) and IR spectroscopy, differential scanning calorimetry (DSC), and elemental analyses. Hydrazinium (3) and 4-amino-1,2,4-triazolium (7) salts crystallized in the monoclinic space group P2(1)/n and have calculated densities of 1.820 and 1.764 g cm -3, respectively. The densities of the energetic salts range between 1.63 and 1.79 g cm -3, as measured by a gas pycnometer. Detonation pressures and detonation velocities were calculated to be 23.1-32.5 GPa and 7740-8790 m s -1, respectively.
KW - density functional calculations
KW - detonation performance
KW - energetic salts
KW - heterocycles
KW - tetrazoles
UR - https://www.scopus.com/pages/publications/84859344531
U2 - 10.1002/asia.201100702
DO - 10.1002/asia.201100702
M3 - Article
AN - SCOPUS:84859344531
SN - 1861-4728
VL - 7
SP - 707
EP - 714
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 4
ER -