NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

Jun Hua Wang; Jian Wen Cheng; Qi Wei; Huan He; Bai Feng Yang; Guo Yu Yang

doi:10.1002/ejic.201402318

NaB₃O₅·0.5H₂O and NH₄NaB₆O₁₀: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

Jun Hua Wang
, Jian Wen Cheng^*
, Qi Wei
, Huan He
, Bai Feng Yang
, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology
Zhejiang Normal University
CAS - Fujian Institute of Research on the Structure of Matter

科研成果: 期刊稿件 › 文章 › 同行评审

39 引用（Scopus）

摘要

Two new cluster open framework borates, NaB₃O₅·0.5H₂O (1) and NH₄NaB₆O₁₀ (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B₃O₇ and B₆O₁₃ cluster units for 1 and 2, in which the B₃O₇ and B₆O₁₃ clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

源语言	英语
页（从-至）	4079-4083
页数	5
期刊	European Journal of Inorganic Chemistry
卷	2014
期	25
DOI	https://doi.org/10.1002/ejic.201402318
出版状态	已出版 - 1 9月 2014

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@article{8949961cdd1d4c8aa1f2c1a766f2d6d8,

title = "NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units",

abstract = "Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.",

keywords = "Borates, Chirality, Luminescence, Open frameworks, Topochemistry",

author = "Wang, \{Jun Hua\} and Cheng, \{Jian Wen\} and Qi Wei and Huan He and Yang, \{Bai Feng\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2014 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2014",

month = sep,

day = "1",

doi = "10.1002/ejic.201402318",

language = "English",

volume = "2014",

pages = "4079--4083",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "25",

}

TY - JOUR

T1 - NaB3O5·0.5H2O and NH4NaB6O10

T2 - Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

AU - Wang, Jun Hua

AU - Cheng, Jian Wen

AU - Wei, Qi

AU - He, Huan

AU - Yang, Bai Feng

AU - Yang, Guo Yu

PY - 2014/9/1

Y1 - 2014/9/1

N2 - Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

AB - Two new cluster open framework borates, NaB3O5·0.5H2O (1) and NH4NaB6O10 (2) have been made under solvothermal conditions and characterized by IR, emission, and diffuse reflectance spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. The common structural features contain the oxoboron cluster building units, B3O7 and B6O13 cluster units for 1 and 2, in which the B3O7 and B6O13 clusters act as 4- and 6-connected nodes to further link each other, resulting in chiral qtz and achiral pcu nets, respectively.

KW - Borates

KW - Chirality

KW - Luminescence

KW - Open frameworks

KW - Topochemistry

UR - https://www.scopus.com/pages/publications/85027930163

U2 - 10.1002/ejic.201402318

DO - 10.1002/ejic.201402318

M3 - Article

AN - SCOPUS:85027930163

SN - 1434-1948

VL - 2014

SP - 4079

EP - 4083

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 25

ER -

NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

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NaB₃O₅·0.5H₂O and NH₄NaB₆O₁₀: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units