Metallophilic attractions between d8-d10 heterometallic compounds trans-[Pt(PH3)2(CN)2] and M(PH3)2+ (M=Ag or Cu): Ab initio study

Bao Hui Xia; Hong Xing Zhang; Yu Qiu Jiao; Qing Jiang Pan; Ze Sheng Li; Chia Chung Sun

doi:10.1063/1.1753563

Metallophilic attractions between d⁸-d¹⁰ heterometallic compounds trans-[Pt(PH₃)₂(CN)₂] and M(PH₃)₂⁺ (M=Ag or Cu): Ab initio study

Bao Hui Xia
, Hong Xing Zhang^*
, Yu Qiu Jiao
, Qing Jiang Pan
, Ze Sheng Li
, Chia Chung Sun

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

源语言	英语
页（从-至）	11487-11492
页数	6
期刊	Journal of Chemical Physics
卷	120
期	24
DOI	https://doi.org/10.1063/1.1753563
出版状态	已出版 - 22 6月 2004
已对外发布	是

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title = "Metallophilic attractions between d8-d10 heterometallic compounds trans-[Pt(PH3)2(CN)2] and M(PH3)2+ (M=Ag or Cu): Ab initio study",

abstract = "Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.",

author = "Xia, \{Bao Hui\} and Zhang, \{Hong Xing\} and Jiao, \{Yu Qiu\} and Pan, \{Qing Jiang\} and Li, \{Ze Sheng\} and Sun, \{Chia Chung\}",

year = "2004",

month = jun,

day = "22",

doi = "10.1063/1.1753563",

language = "English",

volume = "120",

pages = "11487--11492",

journal = "Journal of Chemical Physics",

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publisher = "American Institute of Physics",

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T1 - Metallophilic attractions between d8-d10 heterometallic compounds trans-[Pt(PH3)2(CN)2] and M(PH3)2+ (M=Ag or Cu)

T2 - Ab initio study

AU - Xia, Bao Hui

AU - Zhang, Hong Xing

AU - Jiao, Yu Qiu

AU - Pan, Qing Jiang

AU - Li, Ze Sheng

AU - Sun, Chia Chung

PY - 2004/6/22

Y1 - 2004/6/22

N2 - Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

AB - Investigations of the weak metal-metal interactions of Pt(II)-M(I), where M=Ag, Cu, were carried out through the Ag and Cu model complexes. The existence of weak interaction between Pt(II) and Ag(I)/Cu(I) was confirmed by the obtained attractive interaction energy curves for the metal complexes. It was observed that the estimated equilibrium separations between Pt and M, lie within the region expected for weak metal-metal interaction. It was found that the electronic dispersive contributions dominated the weak interaction.

UR - https://www.scopus.com/pages/publications/3142756578

U2 - 10.1063/1.1753563

DO - 10.1063/1.1753563

M3 - Article

AN - SCOPUS:3142756578

SN - 0021-9606

VL - 120

SP - 11487

EP - 11492

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 24

ER -

Metallophilic attractions between d8-d10 heterometallic compounds trans-[Pt(PH3)2(CN)2] and M(PH3)2+ (M=Ag or Cu): Ab initio study

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Metallophilic attractions between d⁸-d¹⁰ heterometallic compounds trans-[Pt(PH₃)₂(CN)₂] and M(PH₃)₂⁺ (M=Ag or Cu): Ab initio study