Metal-free synthesis of substituted phenols from arylboronic acids in water at room temperature

Min Jiang; Hai Jun Yang; Yong Li; Zhi Ying Jia; Hua Fu

doi:10.1016/j.cclet.2014.03.018

Metal-free synthesis of substituted phenols from arylboronic acids in water at room temperature

Min Jiang
, Hai Jun Yang^*
, Yong Li
, Zhi Ying Jia
, Hua Fu

^*此作品的通讯作者

Tsinghua University

科研成果: 期刊稿件 › 文章 › 同行评审

23 引用（Scopus）

摘要

A convenient, efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed. The protocol uses hydrogen peroxide as a hydroxylating agent, ammonium bicarbonate as an additive, and the reactions were conveniently performed in water at room temperature. The method shows an excellent tolerance of functional groups, so it will find a wide variety of applications in academic and industrial research.

源语言	英语
页（从-至）	715-719
页数	5
期刊	Chinese Chemical Letters
卷	25
期	5
DOI	https://doi.org/10.1016/j.cclet.2014.03.018
出版状态	已出版 - 5月 2014
已对外发布	是

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abstract = "A convenient, efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed. The protocol uses hydrogen peroxide as a hydroxylating agent, ammonium bicarbonate as an additive, and the reactions were conveniently performed in water at room temperature. The method shows an excellent tolerance of functional groups, so it will find a wide variety of applications in academic and industrial research.",

keywords = "Arylboronic acids, Metal-free, Oxidative, Substituted phenols, Synthetic method",

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AU - Jiang, Min

AU - Yang, Hai Jun

AU - Li, Yong

AU - Jia, Zhi Ying

AU - Fu, Hua

PY - 2014/5

Y1 - 2014/5

N2 - A convenient, efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed. The protocol uses hydrogen peroxide as a hydroxylating agent, ammonium bicarbonate as an additive, and the reactions were conveniently performed in water at room temperature. The method shows an excellent tolerance of functional groups, so it will find a wide variety of applications in academic and industrial research.

AB - A convenient, efficient and practical metal-free method for the synthesis of substituted phenols from arylboronic acids has been developed. The protocol uses hydrogen peroxide as a hydroxylating agent, ammonium bicarbonate as an additive, and the reactions were conveniently performed in water at room temperature. The method shows an excellent tolerance of functional groups, so it will find a wide variety of applications in academic and industrial research.

KW - Arylboronic acids

KW - Metal-free

KW - Oxidative

KW - Substituted phenols

KW - Synthetic method

UR - https://www.scopus.com/pages/publications/84901231496

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DO - 10.1016/j.cclet.2014.03.018

M3 - Article

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JO - Chinese Chemical Letters

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ER -

Metal-free synthesis of substituted phenols from arylboronic acids in water at room temperature

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