Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE

Bingjun Li; Yibo Zhao; Guoliang Liu; Xiaomeng Li; Yunjun Luo

doi:10.1007/s10973-016-5524-5

Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE

Bingjun Li
, Yibo Zhao
, Guoliang Liu
, Xiaomeng Li
, Yunjun Luo^*

^*此作品的通讯作者

材料学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

25 引用（Scopus）

摘要

Poly(3,3-bisazidomethyl oxetane) (PBAMO) and glycidyl azide polymer (GAP) were terminated by diisocyanate (TDI) and then extended by 1,4-butanediol (BDO) to synthesis the PBAMO/GAP random block ETPE. The mechanical properties and thermal decomposition behavior of the ETPE were studied by tensile test, differential scanning calorimetry test and thermogravimetric analysis (TG) test. And the thermal decomposition mechanism was studied by TG/Fourier transform infrared/mass spectrometry system. The results indicated that the mechanical properties of the ETPE worked best at w(TDI + BDO) = 30 %. In addition, the ETPE had two decomposition processes, and the gas products mainly come from the first degradation stage of azide groups.

源语言	英语
页（从-至）	717-724
页数	8
期刊	Journal of Thermal Analysis and Calorimetry
卷	126
期	2
DOI	https://doi.org/10.1007/s10973-016-5524-5
出版状态	已出版 - 1 11月 2016

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title = "Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE",

abstract = "Poly(3,3-bisazidomethyl oxetane) (PBAMO) and glycidyl azide polymer (GAP) were terminated by diisocyanate (TDI) and then extended by 1,4-butanediol (BDO) to synthesis the PBAMO/GAP random block ETPE. The mechanical properties and thermal decomposition behavior of the ETPE were studied by tensile test, differential scanning calorimetry test and thermogravimetric analysis (TG) test. And the thermal decomposition mechanism was studied by TG/Fourier transform infrared/mass spectrometry system. The results indicated that the mechanical properties of the ETPE worked best at w(TDI + BDO) = 30 \%. In addition, the ETPE had two decomposition processes, and the gas products mainly come from the first degradation stage of azide groups.",

keywords = "Energetic thermoplastic elastomer, Mechanical properties, Thermal decomposition",

author = "Bingjun Li and Yibo Zhao and Guoliang Liu and Xiaomeng Li and Yunjun Luo",

note = "Publisher Copyright: {\textcopyright} 2016, Akad{\'e}miai Kiad{\'o}, Budapest, Hungary.",

year = "2016",

month = nov,

day = "1",

doi = "10.1007/s10973-016-5524-5",

language = "English",

volume = "126",

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journal = "Journal of Thermal Analysis and Calorimetry",

issn = "1388-6150",

publisher = "Springer Science and Business Media B.V.",

number = "2",

}

TY - JOUR

T1 - Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE

AU - Li, Bingjun

AU - Zhao, Yibo

AU - Liu, Guoliang

AU - Li, Xiaomeng

AU - Luo, Yunjun

PY - 2016/11/1

Y1 - 2016/11/1

N2 - Poly(3,3-bisazidomethyl oxetane) (PBAMO) and glycidyl azide polymer (GAP) were terminated by diisocyanate (TDI) and then extended by 1,4-butanediol (BDO) to synthesis the PBAMO/GAP random block ETPE. The mechanical properties and thermal decomposition behavior of the ETPE were studied by tensile test, differential scanning calorimetry test and thermogravimetric analysis (TG) test. And the thermal decomposition mechanism was studied by TG/Fourier transform infrared/mass spectrometry system. The results indicated that the mechanical properties of the ETPE worked best at w(TDI + BDO) = 30 %. In addition, the ETPE had two decomposition processes, and the gas products mainly come from the first degradation stage of azide groups.

AB - Poly(3,3-bisazidomethyl oxetane) (PBAMO) and glycidyl azide polymer (GAP) were terminated by diisocyanate (TDI) and then extended by 1,4-butanediol (BDO) to synthesis the PBAMO/GAP random block ETPE. The mechanical properties and thermal decomposition behavior of the ETPE were studied by tensile test, differential scanning calorimetry test and thermogravimetric analysis (TG) test. And the thermal decomposition mechanism was studied by TG/Fourier transform infrared/mass spectrometry system. The results indicated that the mechanical properties of the ETPE worked best at w(TDI + BDO) = 30 %. In addition, the ETPE had two decomposition processes, and the gas products mainly come from the first degradation stage of azide groups.

KW - Energetic thermoplastic elastomer

KW - Mechanical properties

KW - Thermal decomposition

UR - https://www.scopus.com/pages/publications/84971673721

U2 - 10.1007/s10973-016-5524-5

DO - 10.1007/s10973-016-5524-5

M3 - Article

AN - SCOPUS:84971673721

SN - 1388-6150

VL - 126

SP - 717

EP - 724

JO - Journal of Thermal Analysis and Calorimetry

JF - Journal of Thermal Analysis and Calorimetry

IS - 2

ER -

Mechanical properties and thermal decomposition of PBAMO/GAP random block ETPE

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