Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite

Dabiao Lu; Denis Sheptyakov; Yingying Cao; Haoting Zhao; Jie Zhang; Maocai Pi; Xubin Ye; Zhehong Liu; Xueqiang Zhang; Zhao Pan; Xingxing Jiang; Zhiwei Hu; Yi feng Yang; Pu Yu; Youwen Long

doi:10.1002/adfm.202411133

Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite

Dabiao Lu
, Denis Sheptyakov
, Yingying Cao
, Haoting Zhao
, Jie Zhang
, Maocai Pi
, Xubin Ye
, Zhehong Liu
, Xueqiang Zhang
, Zhao Pan
, Xingxing Jiang
, Zhiwei Hu
, Yi feng Yang
, Pu Yu
, Youwen Long^*

^*此作品的通讯作者

CAS - Institute of Physics
University of Chinese Academy of Sciences
Paul Scherrer Institute
CAS - Technical Institute of Physics and Chemistry
Max Planck Institute for Chemical Physics of Solids
Songshan Lake Materials Laboratory
Tsinghua University

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe₃Ti₄O₁₂ is reported. In this compound, magnetic Fe²⁺ ions contribute to both ferroelectric and antiferromagnetic orders respectively at T_C ≈107 and T_N ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

源语言	英语
文章编号	2411133
期刊	Advanced Functional Materials
卷	34
期	52
DOI	https://doi.org/10.1002/adfm.202411133
出版状态	已出版 - 23 12月 2024
已对外发布	是

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Lu, D., Sheptyakov, D., Cao, Y., Zhao, H., Zhang, J., Pi, M., Ye, X., Liu, Z., Zhang, X., Pan, Z., Jiang, X., Hu, Z., Yang, Y. F., Yu, P., & Long, Y. (2024). Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite. Advanced Functional Materials, 34(52), 文章 2411133. https://doi.org/10.1002/adfm.202411133

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title = "Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite",

abstract = "Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.",

keywords = "A-site ordered perovskite, displacement-type ferroelectric, high-pressure synthesis, magnetoelectric coupling",

author = "Dabiao Lu and Denis Sheptyakov and Yingying Cao and Haoting Zhao and Jie Zhang and Maocai Pi and Xubin Ye and Zhehong Liu and Xueqiang Zhang and Zhao Pan and Xingxing Jiang and Zhiwei Hu and Yang, \{Yi feng\} and Pu Yu and Youwen Long",

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year = "2024",

month = dec,

day = "23",

doi = "10.1002/adfm.202411133",

language = "English",

volume = "34",

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TY - JOUR

T1 - Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite

AU - Lu, Dabiao

AU - Sheptyakov, Denis

AU - Cao, Yingying

AU - Zhao, Haoting

AU - Zhang, Jie

AU - Pi, Maocai

AU - Ye, Xubin

AU - Liu, Zhehong

AU - Zhang, Xueqiang

AU - Pan, Zhao

AU - Jiang, Xingxing

AU - Hu, Zhiwei

AU - Yang, Yi feng

AU - Yu, Pu

AU - Long, Youwen

PY - 2024/12/23

Y1 - 2024/12/23

N2 - Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

AB - Displacement-type ferroelectrics usually exclude magnetic d-electron contribution. Applying a magnetic field thus can little change the electric polarization. Herein, a magnetic ionic driven displacement-type perovskite ferroelectric CaFe3Ti4O12 is reported. In this compound, magnetic Fe2+ ions contribute to both ferroelectric and antiferromagnetic orders respectively at TC ≈107 and TN ≈ 3.1 K, resulting in coupled electric and magnetic domains. A moderate magnetic field can induce a metamagnetic transition toward ferromagnetic correlations. External magnetic fields can thus readily tune the magnetic and the joint ferroelectric domains, giving rise to exceptional magnetic-field controllable displacement-type polarization with a large magnetoelectric (ME) coupling coefficient. This study opens up a new avenue to find unprecedented ME effects in displacement-type ferroelectrics for numerous applications.

KW - A-site ordered perovskite

KW - displacement-type ferroelectric

KW - high-pressure synthesis

KW - magnetoelectric coupling

UR - https://www.scopus.com/pages/publications/85201187190

U2 - 10.1002/adfm.202411133

DO - 10.1002/adfm.202411133

M3 - Article

AN - SCOPUS:85201187190

SN - 1616-301X

VL - 34

JO - Advanced Functional Materials

JF - Advanced Functional Materials

IS - 52

M1 - 2411133

ER -

Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe2+ Ions in CaFe3Ti4O12 Perovskite

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Magnetic-Field Controllable Displacement-Type Ferroelectricity Driven by Off-Center Fe²⁺ Ions in CaFe₃Ti₄O₁₂ Perovskite