Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

Zhongbao Jian; Dongmei Cui; Zhaomin Hou; Xiaofang Li

doi:10.1039/b926813h

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

Zhongbao Jian
, Dongmei Cui^*
, Zhaomin Hou
, Xiaofang Li

^*此作品的通讯作者

CAS - Changchun Institute of Applied Chemistry
University of Chinese Academy of Sciences
RIKEN

科研成果: 期刊稿件 › 文章 › 同行评审

107 引用（Scopus）

摘要

Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

源语言	英语
页（从-至）	3022-3024
页数	3
期刊	Chemical Communications
卷	46
期	17
DOI	https://doi.org/10.1039/b926813h
出版状态	已出版 - 2010
已对外发布	是

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title = "Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand",

abstract = "Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.",

author = "Zhongbao Jian and Dongmei Cui and Zhaomin Hou and Xiaofang Li",

year = "2010",

doi = "10.1039/b926813h",

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T1 - Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

AU - Jian, Zhongbao

AU - Cui, Dongmei

AU - Hou, Zhaomin

AU - Li, Xiaofang

PY - 2010

Y1 - 2010

N2 - Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

AB - Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

UR - https://www.scopus.com/pages/publications/77950958991

U2 - 10.1039/b926813h

DO - 10.1039/b926813h

M3 - Article

AN - SCOPUS:77950958991

SN - 1359-7345

VL - 46

SP - 3022

EP - 3024

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry- conformation ligand

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