Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

Jian Hao Huang; Cong Cong Jin; Pei Li Xu; Pifu Gong; Zheshuai Lin; Jian Wen Cheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.8b03495

Li₂CsB₇O₁₀(OH)₄: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

Jian Hao Huang
, Cong Cong Jin
, Pei Li Xu
, Pifu Gong
, Zheshuai Lin
, Jian Wen Cheng^*
, Guo Yu Yang

^*此作品的通讯作者

化学与化工学院

Zhejiang Normal University
CAS - Technical Institute of Physics and Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

95 引用（Scopus）

摘要

A new noncentrosymmetric mixed-alkaline borate, Li₂CsB₇O₁₀(OH)₄ (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B₇O₁₂(OH)₄]^7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH₂PO₄), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

源语言	英语
页（从-至）	1755-1758
页数	4
期刊	Inorganic Chemistry
卷	58
期	3
DOI	https://doi.org/10.1021/acs.inorgchem.8b03495
出版状态	已出版 - 4 2月 2019

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@article{cdac8b466b744fbb8e0e30383ccdc870,

title = "Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions",

abstract = "A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.",

author = "Huang, \{Jian Hao\} and Jin, \{Cong Cong\} and Xu, \{Pei Li\} and Pifu Gong and Zheshuai Lin and Cheng, \{Jian Wen\} and Yang, \{Guo Yu\}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = feb,

day = "4",

doi = "10.1021/acs.inorgchem.8b03495",

language = "English",

volume = "58",

pages = "1755--1758",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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}

TY - JOUR

T1 - Li2CsB7O10(OH)4

T2 - A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

AU - Huang, Jian Hao

AU - Jin, Cong Cong

AU - Xu, Pei Li

AU - Gong, Pifu

AU - Lin, Zheshuai

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2019/2/4

Y1 - 2019/2/4

N2 - A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

AB - A new noncentrosymmetric mixed-alkaline borate, Li2CsB7O10(OH)4 (1), was made under solvothermal conditions. This layered boron oxide framework consists of unique bird-shaped [B7O12(OH)4]7- clusters with large 14-ring pores. Its second-harmonic-generation (SHG) signal is 2.5KDP (KH2PO4), with its short ultraviolet (UV) cutoff edge indicating that this crystal is a potential deep-UV transparent nonlinear-optical material.

UR - https://www.scopus.com/pages/publications/85061042617

U2 - 10.1021/acs.inorgchem.8b03495

DO - 10.1021/acs.inorgchem.8b03495

M3 - Article

C2 - 30638369

AN - SCOPUS:85061042617

SN - 0020-1669

VL - 58

SP - 1755

EP - 1758

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

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Li₂CsB₇O₁₀(OH)₄: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions