Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis

Ben Lai Wu; Yan Qing Xu; Ya Qiong Gong; You Gui Huang; Mao Chun Hong

doi:10.1080/00958970701278240

Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis

Ben Lai Wu
, Yan Qing Xu
, Ya Qiong Gong
, You Gui Huang
, Mao Chun Hong^*

^*此作品的通讯作者

CAS - Fujian Institute of Research on the Structure of Matter
Zhengzhou University (ZZU)

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8.

源语言	英语
页（从-至）	2527-2532
页数	6
期刊	Journal of Coordination Chemistry
卷	60
期	23
DOI	https://doi.org/10.1080/00958970701278240
出版状态	已出版 - 12月 2007
已对外发布	是

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@article{968193b933654f8a9c47f9806be43e15,

title = "Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis",

abstract = "The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex \{[Cu2(4PDS)2(ox)(H2O)4](ClO4)2\}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) {\AA} and Z = 8.",

keywords = "Copper(II) complex, Single crystal structure, Situ ligand synthesis",

author = "Wu, \{Ben Lai\} and Xu, \{Yan Qing\} and Gong, \{Ya Qiong\} and Huang, \{You Gui\} and Hong, \{Mao Chun\}",

year = "2007",

month = dec,

doi = "10.1080/00958970701278240",

language = "English",

volume = "60",

pages = "2527--2532",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor and Francis Ltd.",

number = "23",

}

TY - JOUR

T1 - Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis

AU - Wu, Ben Lai

AU - Xu, Yan Qing

AU - Gong, Ya Qiong

AU - Huang, You Gui

AU - Hong, Mao Chun

PY - 2007/12

Y1 - 2007/12

N2 - The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8.

AB - The reaction of 1,3-bis(pyridyl-4-ylthio)propan-2-one with Cu(ClO4)2·6H2O gave a new complex {[Cu2(4PDS)2(ox)(H2O)4](ClO4)2}n (4PDS = 4,4′-dipyridyldisulfide, ox = oxalate), with 4PDS and ox being created by the Cu(II)-assisted oxidation of 1,3-bis(pyridyl-4-ylthio)propan-2-one. The complex determined by X-ray crystallography is a 1D polymer, in which metallacycles formed by two 4PDS and two Cu(II) ions are further bridged through ox anions. It crystallizes in the orthorhombic system, space group Fddd, with lattice parameters a = 15.106(2), b = 23.667(4), c = 27.637(3) Å and Z = 8.

KW - Copper(II) complex

KW - Single crystal structure

KW - Situ ligand synthesis

UR - https://www.scopus.com/pages/publications/35348818668

U2 - 10.1080/00958970701278240

DO - 10.1080/00958970701278240

M3 - Article

AN - SCOPUS:35348818668

SN - 0095-8972

VL - 60

SP - 2527

EP - 2532

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 23

ER -

Linear oxalato- and 4,4′-dipyridyldisulfide-bridged copper(II) coordination polymer involving in situ ligand synthesis

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