Kinetics of thermal degradation of poly(methyl methacrylate) studied with the assistance of the fractional conversion at the maximum reaction rate

Zhiming Gao; Tsuyoshi Kaneko; Dongyan Hou; Masahiro Nakada

doi:10.1016/j.polymdegradstab.2003.11.015

Kinetics of thermal degradation of poly(methyl methacrylate) studied with the assistance of the fractional conversion at the maximum reaction rate

Zhiming Gao^*
, Tsuyoshi Kaneko
, Dongyan Hou
, Masahiro Nakada

^*此作品的通讯作者

化学与化工学院

Chiba Institute of Technology
Anshan Normal University

科研成果: 期刊稿件 › 文章 › 同行评审

76 引用（Scopus）

摘要

One-stage degradation process was observed for a poly(methyl methacrylate) (PMMA) sample. The fractional conversion α_max at the maximum reaction rate is thus applied to determine reaction order of the thermal degradation. It is found that the PMMA degraded in the first order kinetics with weight loss. This is consistent with the fact that PMMA thermally degrades into its monomer. Activation energy was calculated. Compensation effect of the Arrhenius parameters is also found.

源语言	英语
页（从-至）	399-403
页数	5
期刊	Polymer Degradation and Stability
卷	84
期	3
DOI	https://doi.org/10.1016/j.polymdegradstab.2003.11.015
出版状态	已出版 - 6月 2004

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10.1016/j.polymdegradstab.2003.11.015

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abstract = "One-stage degradation process was observed for a poly(methyl methacrylate) (PMMA) sample. The fractional conversion αmax at the maximum reaction rate is thus applied to determine reaction order of the thermal degradation. It is found that the PMMA degraded in the first order kinetics with weight loss. This is consistent with the fact that PMMA thermally degrades into its monomer. Activation energy was calculated. Compensation effect of the Arrhenius parameters is also found.",

keywords = "Compensation effect, Kinetics, PMMA, Reaction order, Thermal degradation",

author = "Zhiming Gao and Tsuyoshi Kaneko and Dongyan Hou and Masahiro Nakada",

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T1 - Kinetics of thermal degradation of poly(methyl methacrylate) studied with the assistance of the fractional conversion at the maximum reaction rate

AU - Gao, Zhiming

AU - Kaneko, Tsuyoshi

AU - Hou, Dongyan

AU - Nakada, Masahiro

PY - 2004/6

Y1 - 2004/6

N2 - One-stage degradation process was observed for a poly(methyl methacrylate) (PMMA) sample. The fractional conversion αmax at the maximum reaction rate is thus applied to determine reaction order of the thermal degradation. It is found that the PMMA degraded in the first order kinetics with weight loss. This is consistent with the fact that PMMA thermally degrades into its monomer. Activation energy was calculated. Compensation effect of the Arrhenius parameters is also found.

AB - One-stage degradation process was observed for a poly(methyl methacrylate) (PMMA) sample. The fractional conversion αmax at the maximum reaction rate is thus applied to determine reaction order of the thermal degradation. It is found that the PMMA degraded in the first order kinetics with weight loss. This is consistent with the fact that PMMA thermally degrades into its monomer. Activation energy was calculated. Compensation effect of the Arrhenius parameters is also found.

KW - Compensation effect

KW - Kinetics

KW - PMMA

KW - Reaction order

KW - Thermal degradation

UR - https://www.scopus.com/pages/publications/2642566958

U2 - 10.1016/j.polymdegradstab.2003.11.015

DO - 10.1016/j.polymdegradstab.2003.11.015

M3 - Article

AN - SCOPUS:2642566958

SN - 0141-3910

VL - 84

SP - 399

EP - 403

JO - Polymer Degradation and Stability

JF - Polymer Degradation and Stability

IS - 3

ER -

Kinetics of thermal degradation of poly(methyl methacrylate) studied with the assistance of the fractional conversion at the maximum reaction rate

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