Kinetics of the thermal decomposition of intercalation compounds during exfoliation

Hui Ren; Fei Yu Kang; Qing Jie Jiao; Qing Zhong Cui

doi:10.1016/s1872-5805(07)60003-1

Kinetics of the thermal decomposition of intercalation compounds during exfoliation

Hui Ren^*
, Fei Yu Kang
, Qing Jie Jiao
, Qing Zhong Cui

^*此作品的通讯作者

机电学院

Tsinghua University
Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

The phase transformations and thermal decomposition of the following graphite intercalation compounds (GICs), HNO₃-CH₃COOH-GIC, H₂SO₄-GIC and H₂SO₄-CH₃COOH-GIC, were measured by an FTIR-associated TG apparatus. Using Kissinger and Ozawa principles, the kinetic parameters of some typical exfoliation reactions were evaluated and the thermal decomposition mechanism of the exfoliation process was determined. When the heating rate was in the range of 20-80°C/min, the activation energies of the exfoliation reactions were all less than 120 kJ/mol.

源语言	英语
页（从-至）	315-319
页数	5
期刊	Xinxing Tan Cailiao/New Carbon Materials
卷	21
期	4
DOI	https://doi.org/10.1016/s1872-5805(07)60003-1
出版状态	已出版 - 12月 2006

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@article{bbfc9859263e4cd1bc5c6a3296cd21b9,

title = "Kinetics of the thermal decomposition of intercalation compounds during exfoliation",

abstract = "The phase transformations and thermal decomposition of the following graphite intercalation compounds (GICs), HNO3-CH3COOH-GIC, H2SO4-GIC and H2SO4-CH3COOH-GIC, were measured by an FTIR-associated TG apparatus. Using Kissinger and Ozawa principles, the kinetic parameters of some typical exfoliation reactions were evaluated and the thermal decomposition mechanism of the exfoliation process was determined. When the heating rate was in the range of 20-80°C/min, the activation energies of the exfoliation reactions were all less than 120 kJ/mol.",

keywords = "Exfoliation, Intercalation, Kinetics, Thermal analysis",

author = "Hui Ren and Kang, \{Fei Yu\} and Jiao, \{Qing Jie\} and Cui, \{Qing Zhong\}",

year = "2006",

month = dec,

doi = "10.1016/s1872-5805(07)60003-1",

language = "English",

volume = "21",

pages = "315--319",

journal = "Xinxing Tan Cailiao/New Carbon Materials",

issn = "2097-1605",

publisher = "Science Press",

number = "4",

}

TY - JOUR

T1 - Kinetics of the thermal decomposition of intercalation compounds during exfoliation

AU - Ren, Hui

AU - Kang, Fei Yu

AU - Jiao, Qing Jie

AU - Cui, Qing Zhong

PY - 2006/12

Y1 - 2006/12

N2 - The phase transformations and thermal decomposition of the following graphite intercalation compounds (GICs), HNO3-CH3COOH-GIC, H2SO4-GIC and H2SO4-CH3COOH-GIC, were measured by an FTIR-associated TG apparatus. Using Kissinger and Ozawa principles, the kinetic parameters of some typical exfoliation reactions were evaluated and the thermal decomposition mechanism of the exfoliation process was determined. When the heating rate was in the range of 20-80°C/min, the activation energies of the exfoliation reactions were all less than 120 kJ/mol.

AB - The phase transformations and thermal decomposition of the following graphite intercalation compounds (GICs), HNO3-CH3COOH-GIC, H2SO4-GIC and H2SO4-CH3COOH-GIC, were measured by an FTIR-associated TG apparatus. Using Kissinger and Ozawa principles, the kinetic parameters of some typical exfoliation reactions were evaluated and the thermal decomposition mechanism of the exfoliation process was determined. When the heating rate was in the range of 20-80°C/min, the activation energies of the exfoliation reactions were all less than 120 kJ/mol.

KW - Exfoliation

KW - Intercalation

KW - Kinetics

KW - Thermal analysis

UR - https://www.scopus.com/pages/publications/33846527996

U2 - 10.1016/s1872-5805(07)60003-1

DO - 10.1016/s1872-5805(07)60003-1

M3 - Article

AN - SCOPUS:33846527996

SN - 2097-1605

VL - 21

SP - 315

EP - 319

JO - Xinxing Tan Cailiao/New Carbon Materials

JF - Xinxing Tan Cailiao/New Carbon Materials

IS - 4

ER -

Kinetics of the thermal decomposition of intercalation compounds during exfoliation

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