TY - JOUR
T1 - Isothermal hazards evaluation of benzoyl peroxide mixed with benzoic acid via TAM III test
AU - Wang, Tien Szu
AU - Liu, Shang Hao
AU - Qian, Xin Ming
AU - You, Mei Li
AU - Chou, Wei Lung
AU - Shu, Chi Min
PY - 2013/9
Y1 - 2013/9
N2 - Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E a), frequency factor (A), heat of decomposition (ΔH d), and time to maximum rate under isothermal conditions (TMR iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.
AB - Isothermal microcalorimetry can be used to investigate the thermokinetic parameters for reactive mechanisms. Benzoyl peroxide (BPO), a typical organic peroxide, undergoes an autocatalytic reaction under isothermal decomposition. It requires intrinsically safer design of preparation, manufacturing, transportation, storage, and even disposal. The scope of this study was to describe the exothermic reaction and reaction model of BPO and mixed with benzoic acid by the thermal activity monitor III (TAM III). The results showed the isothermal kinetic parameters, such as activation energy (E a), frequency factor (A), heat of decomposition (ΔH d), and time to maximum rate under isothermal conditions (TMR iso), which were necessary and useful to insure safe storage or transportation for self-reactive substances applied in the process industries.
KW - Autocatalytic reaction
KW - Intrinsically safer design
KW - Isothermal kinetic parameters
KW - Process industries
KW - Thermal activity monitor III (TAM III)
KW - Thermokinetic parameters
UR - https://www.scopus.com/pages/publications/84883149851
U2 - 10.1007/s10973-013-3020-8
DO - 10.1007/s10973-013-3020-8
M3 - Article
AN - SCOPUS:84883149851
SN - 1388-6150
VL - 113
SP - 1625
EP - 1631
JO - Journal of Thermal Analysis and Calorimetry
JF - Journal of Thermal Analysis and Calorimetry
IS - 3
ER -