Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines

Chaoyuan Zeng; Fan Yang; Jingchao Chen; Jun Wang; Baomin Fan

doi:10.1039/c5ob01243k

Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines

Chaoyuan Zeng
, Fan Yang
, Jingchao Chen
, Jun Wang^*
, Baomin Fan

^*此作品的通讯作者

Yunnan Minzu University
Southern University of Science and Technology

科研成果: 期刊稿件 › 文章 › 同行评审

36 引用（Scopus）

摘要

A combination of iridium/copper associated with (R)-Difluorphos catalyst for the asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed, which afforded chiral trans-vicinal diamines in 80-97% yields with 93-95% enantioselectivities.

源语言	英语
页（从-至）	8425-8428
页数	4
期刊	Organic and Biomolecular Chemistry
卷	13
期	31
DOI	https://doi.org/10.1039/c5ob01243k
出版状态	已出版 - 21 8月 2015
已对外发布	是

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10.1039/c5ob01243k

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title = "Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines",

abstract = "A combination of iridium/copper associated with (R)-Difluorphos catalyst for the asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed, which afforded chiral trans-vicinal diamines in 80-97\% yields with 93-95\% enantioselectivities.",

author = "Chaoyuan Zeng and Fan Yang and Jingchao Chen and Jun Wang and Baomin Fan",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

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AU - Zeng, Chaoyuan

AU - Yang, Fan

AU - Chen, Jingchao

AU - Wang, Jun

AU - Fan, Baomin

PY - 2015/8/21

Y1 - 2015/8/21

N2 - A combination of iridium/copper associated with (R)-Difluorphos catalyst for the asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed, which afforded chiral trans-vicinal diamines in 80-97% yields with 93-95% enantioselectivities.

AB - A combination of iridium/copper associated with (R)-Difluorphos catalyst for the asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed, which afforded chiral trans-vicinal diamines in 80-97% yields with 93-95% enantioselectivities.

UR - https://www.scopus.com/pages/publications/84938383740

U2 - 10.1039/c5ob01243k

DO - 10.1039/c5ob01243k

M3 - Article

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EP - 8428

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

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ER -

Iridium/copper-cocatalyzed asymmetric ring opening reaction of azabenzonorbornadienes with amines

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