TY - JOUR
T1 - Investigation into antimony pentafluoride-based catalyst in preparing organo-fluorine compounds
AU - Yang, Hui E.
AU - Quan, Heng Dao
AU - Tamura, Masanori
AU - Sekiya, Akira
PY - 2005/5/24
Y1 - 2005/5/24
N2 - Antimony pentafluoride (SbF5)/porous metal fluorides (PMF) were prepared by impregnating PMF with SbCl5, and then fluorinating with anhydrous hydrogen fluoride (AHF). It demonstrates excellent activity in vapor-phase catalytic fluorination and overcomes such drawbacks as hygroscopicity, corrosion and toxicity that appear while SbF5 was used alone. Furthermore, SbF5/PMF was characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, BET surface area measurement and SEM. Its catalytic activity was evaluated for vapor-phased fixed-bed catalytic fluorination.
AB - Antimony pentafluoride (SbF5)/porous metal fluorides (PMF) were prepared by impregnating PMF with SbCl5, and then fluorinating with anhydrous hydrogen fluoride (AHF). It demonstrates excellent activity in vapor-phase catalytic fluorination and overcomes such drawbacks as hygroscopicity, corrosion and toxicity that appear while SbF5 was used alone. Furthermore, SbF5/PMF was characterized by means of X-ray diffraction, X-ray photoelectron spectroscopy, BET surface area measurement and SEM. Its catalytic activity was evaluated for vapor-phased fixed-bed catalytic fluorination.
KW - Anhydrous hydrogen fluoride (AHF)
KW - Antimony pentachloride
KW - Antimony pentafluoride
KW - Organo-fluorine compounds
KW - Porous metal fluorides
UR - https://www.scopus.com/pages/publications/15944379874
U2 - 10.1016/j.molcata.2004.12.040
DO - 10.1016/j.molcata.2004.12.040
M3 - Article
AN - SCOPUS:15944379874
SN - 1381-1169
VL - 233
SP - 99
EP - 104
JO - Journal of Molecular Catalysis A: Chemical
JF - Journal of Molecular Catalysis A: Chemical
IS - 1-2
ER -