Intermolecular formyloxyarylation of alkenes by photoredox meerwein reaction

Chang Jiang Yao; Qiu Sun; Namrata Rastogi; Burkhard König

doi:10.1021/acscatal.5b00314

Intermolecular formyloxyarylation of alkenes by photoredox meerwein reaction

Chang Jiang Yao
, Qiu Sun
, Namrata Rastogi
, Burkhard König^*

^*此作品的通讯作者

University of Regensburg
CAS - Institute of Chemistry

科研成果: 期刊稿件 › 文章 › 同行评审

68 引用（Scopus）

摘要

The intermolecular formyloxylation-arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product.

源语言	英语
页（从-至）	2935-2938
页数	4
期刊	ACS Catalysis
卷	5
期	5
DOI	https://doi.org/10.1021/acscatal.5b00314
出版状态	已出版 - 1 5月 2015
已对外发布	是

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title = "Intermolecular formyloxyarylation of alkenes by photoredox meerwein reaction",

abstract = "The intermolecular formyloxylation-arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76\%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product.",

keywords = "Meerwein reaction, N, N -dimethylformamide, diazonium salts, formyloxylation-arylation, photocatalysis",

author = "Yao, \{Chang Jiang\} and Qiu Sun and Namrata Rastogi and Burkhard K{\"o}nig",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2015",

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doi = "10.1021/acscatal.5b00314",

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T1 - Intermolecular formyloxyarylation of alkenes by photoredox meerwein reaction

AU - Yao, Chang Jiang

AU - Sun, Qiu

AU - Rastogi, Namrata

AU - König, Burkhard

PY - 2015/5/1

Y1 - 2015/5/1

N2 - The intermolecular formyloxylation-arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product.

AB - The intermolecular formyloxylation-arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product.

KW - Meerwein reaction

KW - N, N -dimethylformamide

KW - diazonium salts

KW - formyloxylation-arylation

KW - photocatalysis

UR - https://www.scopus.com/pages/publications/84928944468

U2 - 10.1021/acscatal.5b00314

DO - 10.1021/acscatal.5b00314

M3 - Article

AN - SCOPUS:84928944468

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JO - ACS Catalysis

JF - ACS Catalysis

IS - 5

ER -

Intermolecular formyloxyarylation of alkenes by photoredox meerwein reaction

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